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Copolymerization without initiator ofN-(2-hydroxyethyl)ethyleneimine with succinic anhydride

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Summary

Copolymers of N-(2-hydroxyethyl)ethyleneimine and succinic anhydride without initiator were prepared under different experimental conditions. The composition of the copolymers was determined by elemental analyses and1H-NMR spectroscopy. From the results of FT-IR and1H-NMR spectroscopy a scheme of copolymerization via zwitterion is presented which includes an esterification reaction of the pendant hydroxylic groups.

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Authors and Affiliations

  1. Departmento de Polimeros, Facultad de Ciencias Químicas, Universidad de Concepción, Casilla 3-C, Concepción, Chile

    S. A. Pooley, G. S. Canessa, B. L. Rivas & E. Espejo

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  1. S. A. Pooley
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  2. G. S. Canessa
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  3. B. L. Rivas
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  4. E. Espejo
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Pooley, S.A., Canessa, G.S., Rivas, B.L. et al. Copolymerization without initiator ofN-(2-hydroxyethyl)ethyleneimine with succinic anhydride. Polymer Bulletin 35, 271–277 (1995). https://doi.org/10.1007/BF00963123

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  • DOI: https://doi.org/10.1007/BF00963123

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