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Kinetics and mechanism of the reduction of polychloroalkanes by triethylsilane, catalyzed by binuclear manganese and rhenium carbonyls

  • Organic Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Kinetic methods have been used to show that the hydrides HM(CO)5 formed in the systems M2(CO)10 + HSiEt3 (M=Mn and Re) are involved in chain transfer at the chlorinated radicals.

  2. 2.

    The formation of HRe(CO)5 in the photochemical reaction of Re2(CO)10 with HSiEt3 has been shown by UV spectroscopy.

  3. 3.

    The system Mn2(CO)10 + HSiEt3 has been shown for the first time to be capable or reducing 1,1-dichloroalkanes.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow

    L. V. Il'inskaya, N. A. Kuz'mina, R. G. Gasanov & E. Ts. Chukovskaya

Authors
  1. L. V. Il'inskaya
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  2. N. A. Kuz'mina
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  3. R. G. Gasanov
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  4. E. Ts. Chukovskaya
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2253–2256, October, 1987.

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Il'inskaya, L.V., Kuz'mina, N.A., Gasanov, R.G. et al. Kinetics and mechanism of the reduction of polychloroalkanes by triethylsilane, catalyzed by binuclear manganese and rhenium carbonyls. Russ Chem Bull 36, 2087–2090 (1987). https://doi.org/10.1007/BF00961992

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  • DOI: https://doi.org/10.1007/BF00961992

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