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Reaction chromato-spectrometry in the series of 1-aryl-2-(2-furyl) cyclopropanes

  • Organic Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    A pulse microreactor was used in an admission system of a chromatomass spectrometer, and it was found that gas-phase hydrogenolysis (Pd/porous glass) of l-aryl-2-(2-furyl) cyclopropanes at 200–250°C proceeds with the formation of l-aryl-3-(2-furyl) propanes and 1(2)-aryl-2(l)-(2-furyl) propanes in 9:1 ratio.

  2. 2.

    l-Aryl-3-(2-furyl) propanes undergo unusual fragmentation under electron impact to form stable cation radicals of alkylstyrenes, while fragmentation typical of alkylbenzenes and alkylfurans is less evident.

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Literature cited

  1. A. I. Mikaya, L. P. Medvedkova, V. G. Zaikin, V. M. Vdovin, and A. A. Kamyshova, Izv. Akad. Nauk SSSR, Ser. Khim., 1181 (1983).

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Authors and Affiliations

  1. A. V. Topchiev Institute of Petrochemical Synthesis, Academy of Sciences of the USSR, Moscow

    A. I. Mikaya, V. G. Zaikin & M. V. Tsodikov

Authors
  1. A. I. Mikaya
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  2. V. G. Zaikin
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  3. M. V. Tsodikov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 11, pp. 2494–2497, November, 1986.

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Mikaya, A.I., Zaikin, V.G. & Tsodikov, M.V. Reaction chromato-spectrometry in the series of 1-aryl-2-(2-furyl) cyclopropanes. Russ Chem Bull 35, 2282–2284 (1986). https://doi.org/10.1007/BF00953340

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  • DOI: https://doi.org/10.1007/BF00953340

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