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Photochemical reaction of phosphine hydride complexes of molybdenum and tungsten with molecular nitrogen

  • Inorganic Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    During irradiation with light with a wavelength <500 nm, phosphine hydride complexes MH4L4, where M=Mo or W and L=PMePh2 or 1/2Ph2PCH2CH2PPh2, react with molecular nitrogen with formation of trans-dinitrogen complexes M(N2)2L4.

  2. 2.

    The reactivity of phosphine hydride complexes of molybdenum in this photoreaction is higher than that of analogs of tungsten.

  3. 3.

    The formation mechanisms of trans-dinitrogen complexes of molybdenum with monodentate and bidentate ligands are very different.

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Author information

Authors and Affiliations

  1. Department of the Institute of Chemical Physics, Academy of Sciences of the USSR, Chernogolovka

    A. P. Pivovarov, Yu. V. Gak, T. N. Doronina, V. D. Makhaev, A. P. Borisov & Yu. G. Borod'ko

Authors
  1. A. P. Pivovarov
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  2. Yu. V. Gak
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  3. T. N. Doronina
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  4. V. D. Makhaev
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  5. A. P. Borisov
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  6. Yu. G. Borod'ko
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Additional information

Translated from Izvestiya Akademii Nauk SSSR., Seriya Khimicheskaya, No. 6, pp. 1207–1212, June, 1981.

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Pivovarov, A.P., Gak, Y.V., Doronina, T.N. et al. Photochemical reaction of phosphine hydride complexes of molybdenum and tungsten with molecular nitrogen. Russ Chem Bull 30, 947–952 (1981). https://doi.org/10.1007/BF00950268

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  • DOI: https://doi.org/10.1007/BF00950268

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