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Spatial structure of phosphorus-containing heterocycles. 23. 2-Phenoxy-1,3,2-dioxaphosphorinanes with four-coordinate phosphorus

  • Physical Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The change in the valence state of the phosphorus atom influences the orientation with respect to the P-O(Ph) bond in 2-phenoxy-2-oxo(thiono)-1,3,2-dioxaphosphorinanes.

  2. 2.

    An orthogonal conformation is realized in the O-Ph fragment of the compounds investigated, regardless of the hybridization of the phosphorus.

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Authors and Affiliations

  1. A. M. Butlerov Chemical Institute, USSR

    R. P. Arshinova, T. D. Sorokina, A. B. Remizov, G. E. Koroleva & B. A. Arbuzov

  2. V. I. Ul'yanov-Lenin Kazan State University, USSR

    R. P. Arshinova, T. D. Sorokina, A. B. Remizov, G. E. Koroleva & B. A. Arbuzov

Authors
  1. R. P. Arshinova
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  2. T. D. Sorokina
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  3. A. B. Remizov
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  4. G. E. Koroleva
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  5. B. A. Arbuzov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2242–2247, October, 1979.

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Arshinova, R.P., Sorokina, T.D., Remizov, A.B. et al. Spatial structure of phosphorus-containing heterocycles. 23. 2-Phenoxy-1,3,2-dioxaphosphorinanes with four-coordinate phosphorus. Russ Chem Bull 28, 2065–2070 (1979). https://doi.org/10.1007/BF00947554

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  • DOI: https://doi.org/10.1007/BF00947554

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