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Electron interactions and infrared spectra of para isomers of X(CF3Y)C6H4 compounds

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Abstract

IR spectra are reported for

, in which X represents various polar substituents and Y a bridge with multiple bonds. There is a linear relation between the frequency of the vE C-F(H) degenerate vibration and Taft's induction constant σ* for the radical attached to the CF3 group. Frequency vE C-F is also correlated with the σn, which shows that the conjugated system can transmit the electron effect of X to the CF3 group. Compounds are compared as regards this transmission, and some features of the frequencies of the multiple bonds are elucidated.

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References

  1. V. F. Kulik, Yu. P. Egorov, M. S. Marenets, and L. M. Yagupol'skii, Zh. Strukt. Khim., 4, 541, 1963.

    Google Scholar 

  2. V. F. Kulik, Yu. P. Egorov, V. V. Orda, and L. M. Yagupol'skii, Zh. Prikl. Spektr., 1965.

  3. C. V. Berney, Spectrochim. Acta, 20, 37, 1964.

    Google Scholar 

  4. R. R. Randle and D. H. Whiffen, J. Chem. Soc., 1311, 1955.

  5. S. N. Nabi and N. Sheppard, J. Chem., Soc. 3439, 1959.

  6. Yu. P. Egorov, V. F. Lokhmachev, and L. M. Yagupol'skii, Izv. Akad. Nauk SSSR, ser. fiz., 26, 1276, 1962.

    Google Scholar 

  7. L. M. Yagupol'skii, A. G. Panteleimonov, and V. V. Orda, Zh. Obshchei Khim., 34, 3456, 1964.

    Google Scholar 

  8. L. M. Yagupol'skii and Yu. A. Failkov, Zh. Obshchei Khim., 30, 129, 1960.

    Google Scholar 

  9. L. M. Yagupol'skii and Yu. A. Failkov, Zh. Obshchei Khim., 31, 3586, 1961.

    Google Scholar 

  10. A. M. Bogomolov, Optika i Spektroskopiya, 12, 186, 1962.

    Google Scholar 

  11. E. E. Ferguson, L. McKelsen, and O. R. Nielsen, J. Chem. Phys., 21, 1733, 1953.

    Google Scholar 

  12. V. A. Pal'm, Usp. Khim., 30, 1069, 1961.

    Google Scholar 

  13. A. E. Lutskii et al., Zh. Obshchei Khim., 1965.965.

  14. L. Bellamy, Infrared Spectra of Complex Molecules [Russian translation], IL, Moscow, 1963.

    Google Scholar 

  15. J. H. Wotiz, F. A. Miller, and R. J. Palchak, J. Am. Chem. Soc., 72, 5055, 1950.

    Google Scholar 

  16. R. N. Sterbin and S. S. Dubov, Zh. Vses. Khim. Obshch., 7, 117, 1962.

    Google Scholar 

  17. H. J. Boonstra and L. C. Rinzema, Rec. trav. Chim., 79, 962, 1960.

    Google Scholar 

  18. C. C. Price and R. G. Gillis, J. Am. Chem. Soc., 75, 4750, 1953.

    Google Scholar 

  19. P. P. Shorygin, M. F. Shostakovskii, E. N. Prilezhaeva, et al., Izv. Akad. Nauk SSSR, Otdel. Khim. Nauk, 1571, 1961.

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Authors and Affiliations

  1. Institute of the Chemistry of Macromolecular Compounds, AS UkrSSR, Kiev

    V. F. Kulik, Yu. P. Egorov, A. G. Panteleimonov, Yu. A. Fialkov & L. M. Yagupol'skii

  2. Institute of Organic Chemistry, AS UkrSSR, Kiev

    V. F. Kulik, Yu. P. Egorov, A. G. Panteleimonov, Yu. A. Fialkov & L. M. Yagupol'skii

Authors
  1. V. F. Kulik
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  2. Yu. P. Egorov
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  3. A. G. Panteleimonov
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  4. Yu. A. Fialkov
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  5. L. M. Yagupol'skii
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Additional information

See[6, 7] for brief details of the spectra of some of the compounds.

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Kulik, V.F., Egorov, Y.P., Panteleimonov, A.G. et al. Electron interactions and infrared spectra of para isomers of X(CF3Y)C6H4 compounds. Theor Exp Chem 1, 107–112 (1965). https://doi.org/10.1007/BF00945568

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  • DOI: https://doi.org/10.1007/BF00945568

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