Abstract
Mass spectrometry has been applied in an investigation of fluorinated β-diketones and the decomposition of these compounds under electron impact. It has been shown that there is a possibility that intramolecular hydrogen bonds of the -H...O= and-H...F- types may exist in the fluorinated β-diketones and the products of their decomposition in the gas phase, these bonds playing an important role in the mechanism of fragmentation. The formation of cyclic structures in this process is postulated.
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Translated from Teoreticheskaya i Éksperimental'naya Khimiya, Vol. 21, No. 2, pp. 182–187, March–April, 1985.
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Lozinskii, M.O., Fialkov, Y.A., Khomenko, V.S. et al. Mass spectrometric study of fluorinated β-diketones. Theor Exp Chem 21, 174–179 (1985). https://doi.org/10.1007/BF00945192
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DOI: https://doi.org/10.1007/BF00945192