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Equilibria in complexes ofN-Heterocyclic molecules, part XXIII. Reaction of hydroxide ion with bis-[2,4,6-tri-(2-pyridyl)-1,3,5-triazine] cobalt(II) and nickel(II)

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Summary

The reactions of [Ni(TPT)2]2+ and [Co(TPT)2]2+ with aqueous hydroxide ion involve the formation of pseudo-base species prior to the dissociation of a ligand molecule. The [M(TPT)(H2O)3]2+ or [M(TPT)(OH)3]− species thus formed react further with hydroxide ion to yield compounds previously described. The kinetics of pseudo-base formation have been followed in each case and the results are compared with a number of other reactions of analogous compounds with hydroxide ion and with water.

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Authors and Affiliations

  1. Department of Inorganic Chemistry, University College, P.O. Box 78, CF1 1XL, Cardiff, UK

    Peter A. Williams

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  1. Peter A. Williams
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Part XXII, ref. 3.

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Williams, P.A. Equilibria in complexes ofN-Heterocyclic molecules, part XXIII. Reaction of hydroxide ion with bis-[2,4,6-tri-(2-pyridyl)-1,3,5-triazine] cobalt(II) and nickel(II). Transition Met Chem 4, 24–27 (1979). https://doi.org/10.1007/BF00941011

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  • DOI: https://doi.org/10.1007/BF00941011

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