Conclusions
A study of the low-temperature addition of chlorine fluorosulfate to olefins in the presence of perfluorocarboxylic acids has yielded support for the electrophilic mechanism for this reaction.
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Literature cited
A. V. Fokin, Yu. N. Studnev, L. D. Kuznetsova, and V. L. Rud', Izv. Akad. Nauk SSSR, Ser. Khim., 471 (1974).
D. D. Moldavskii, V. G. Temchenko, and G. A. Antipenko, Zh. Org. Khim.,7, 44 (1971).
D. D. Moldavskii, V. G. Temchenko, V. I. Slesareva, and G. A. Antipenko, Zh. Org. Khim.,9, 633 (1973).
W. P. Gilbreath and G. H. Cady, Inorg. Chem.,2, 496 (1963).
A. V. Fokin, A. D. Nikolaeva, Yu. S. Studnev, A. I. Rapkin, N. A. Proshin, and L. D. Kuznetsova, Izv. Akad. Nauk SSSR, Ser. Khim., 1000 (1975).
M. Hauptschein and M. Braid, J. Am. Chem. Soc.,83, 2505 (1961).
A. V. Fokin, Yu. N. Studnev, A. I. Rapkin, and L. D. Kuznetsova, Izv. Akad. Nauk SSSR, Ser. Khim., 1892 (1974).
H. H. Gibbs, W. L. Endens, and R. N. Griffin, J. Org. Chem.,26, 4140 (1961).
R. N. Haszeldine, Nature,168, 1028 (1951).
R. A. De Marco, D. A. Couch, and J. M. Shreeve, J. Org. Chem.,37, 3332 (1972).
M. M. Boudakian, G. A. Hyde, and S. Kongpricha, J. Org. Chem.,36, 940 (1971).
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 649–651, March, 1978.
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Fokin, A.V., Studnev, Y.N., Kuznetsova, L.D. et al. Chlorine fluorosulfate. Russ Chem Bull 27, 559–560 (1978). https://doi.org/10.1007/BF00923937
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DOI: https://doi.org/10.1007/BF00923937