Summary
In the hydrogenation of α-alkylfurfuryl alcohols in the vapor phase over an Ni-ZnO catalyst at 200–250°, reduction of the hydroxy group occurs with formation of 2-alkylfurans; these compounds are converted, partially or completely according to the temperature, into the corresponding aliphatic ketones as a result of the hydrogenolysis of the ring at the C-O bond.
Literature cited
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N. I. Shuikin and I. F. Bel'skii, Proc. Acad. Sci. USSR 117, 95 (1957).
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Shuikin, N.I., Bel'skii, I.F. Hydrogenation of α-alkylfurfuryl alcohols over an Ni-ZnO catalyst. Russ Chem Bull 7, 487–488 (1958). https://doi.org/10.1007/BF00910942
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DOI: https://doi.org/10.1007/BF00910942