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Chemistry of polyenic and polyacetylenic compounds

Communication 7. Study of the hydration of ethylenic acetylenic alcohols

  • Organic and Biological Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    The hydration of ethylenic acetylenic alcohols in presence of mercuric acetate in acetic acid is not accompanied by secondary isomerization processes and gives the corresponding unsaturated α-ketol acetic esters in high yields.

  2. 2.

    The pyrolysis of the acetic esters of 3-hydroxy-3,4-dimethyl-4-penten-2-one (II) and 3-hydroxy-4hexen-2-one (XIII) was studied, and the dienes (V) and (XIV) were obtained in satisfactory yields.

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Authors and Affiliations

  1. N. D Zelinskii Institute of Organic Chemistry, Academy of Sciences, USSR

    M. V. Mavrov & V. F. Kucherov

Authors
  1. M. V. Mavrov
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  2. V. F. Kucherov
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Mavrov, M.V., Kucherov, V.F. Chemistry of polyenic and polyacetylenic compounds. Russ Chem Bull 11, 1190–1196 (1962). https://doi.org/10.1007/BF00908398

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  • DOI: https://doi.org/10.1007/BF00908398

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