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Paper electrophoresis and x-ray structure study of the complex compounds of phenols with germanium

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    The polyphenols catechol and pyrogallol, as well as phenolic compounds of more complex composition (d,l-catechin,l-epicatechin, tannin), having hydroxyl groups in the ortho position, form stable complex compounds with germanium over a large range of pH values.

  2. 2.

    An x-ray structure study of the complex compounds of germanium with catechol has shown that these compounds have a crystalline structure, and do not contain any admixture of germanium or catechol.

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Literature cited

  1. I. N. Antipov-Karataev, Pochvovedenie No. 11, 28 (1957).

    Google Scholar 

  2. H. J. Atkinson and J. R. Wright, Soil Sci.84, No. 1 (1957).

  3. J. M. Bremner, S. C. Heintze, P. J. Mann, and H. Lees, Nature158, 790 (1946).

    Google Scholar 

  4. S. Fallab, M. Schuster, and H. Erlenmeyer, Experientia12, No. 6 (1956).

  5. S. M. Manskaya and T. V. Drozdova, Use of Microelements in Agriculture and Medicine [in Russian] (Riga, 1959) p. 115.

  6. S. M. Manskaya, T. V. Drozdova, and M. P. Emel'yanova, Geokhimiya No. 6, 529 (1960).

    Google Scholar 

  7. S. M. Manskaya, T. V. Drozdova, R. P. Kravtsova, and K. I. Tobelko, Geokhimiya No. 5, 432 (1961).

    Google Scholar 

  8. R. E. Weinland and W. Denzel, Ber.45, 148, 1113 (1912).

    Google Scholar 

  9. A. K. Babko, Physicochemical Analysis of Complex Compounds in Solutions [in Russian] (AN SSSR Press, Kiev. 1955).

    Google Scholar 

  10. G. P. Haight and V. Paracamian, Analyt. Chem.32, No. 6. 642 (1960).

    Google Scholar 

  11. S. Ya. Shnaiderman, Izv. vysshikh uchebnykh zaved. “Khim. i khim. tekhnologiya” No. 2, 258 (1960).

    Google Scholar 

  12. V. I. Kuznetsov, Trudy po khimii i khimicheskoi tekhnologii Part 3. No. 3, 359 (1960).

    Google Scholar 

  13. J. Halmekoski, Annals Acad. Sci. Fennice, Ser. A., II, Chemica7 (1959).

  14. P. Bevillard, Compt. rend. No. 7, 2606 (1952).

    Google Scholar 

  15. P. Bevillard, Bull. Soc. chim. France No. 3, 296 (1954).

    Google Scholar 

  16. P. Bevillard, Bull. Soc. chim. France No. 3, 304 (1954).

    Google Scholar 

  17. Takuji Kanno, Scient. Repts. Res. Inst. Tohoku Univ. Ser. A,12, No. 2, 175 (1960).

    Google Scholar 

  18. H. Berbalk and J. Szaboles, Monatsh. Chem.90, No. 2, 198 (1959).

    Google Scholar 

  19. T. V. Drozdova and M. P. Emel'yanova, Dokl. AN SSSR131, No. 3, 651 (1960).

    Google Scholar 

  20. F. Klinehammer, Naturwiss.45, No. 23, 571 (1958).

    Google Scholar 

  21. J. B. Pridham, J. Chromatography2, No. 6, 605 (1959).

    Google Scholar 

  22. F. Feigl, Spot Tests in Inorganic Analysis (Amsterdam, 1958).

  23. V. A. Nazarenko, N. V. Lebedeva, and R. V. Ravitskaya, Zavodsk. laboratoriya No. 1, 9 (1958).

    Google Scholar 

  24. V. I. Kuznetsov, Chemical Reagents and Preparations [in Russian] (Goskhimizdat, 1953).

  25. P. J. Antikainen, Suomen kem.B32, No. 10, 211 (1959).

    Google Scholar 

  26. I. P. Alimarin, Transactions of the All-Union Conference on Analytical Chemistry [in Russian] Part 2 (1948), p. 371. All abbreviations of periodicals in the above bibliography are letter-by-letter transliterations of the abbreviations as given in the original Russian journal.Some or all of this peri- odical literature may well be available in English translation. A complete list of the cover-to- cover English translations appears at the back of this issue.

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Authors and Affiliations

  1. V. I. Verpadskii Institute of Geochemistry and Analytical Chemistry, Academy of Sciences of the USSR, USSR

    T. V. Drozdova, R. P. Kravtsova & K. I. Tobelko

Authors
  1. T. V. Drozdova
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  2. R. P. Kravtsova
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  3. K. I. Tobelko
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Additional information

We should like to use this occasion to express our gratitude to M. N. Zaprometov for supplying us with the catechin samples.

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Drozdova, T.V., Kravtsova, R.P. & Tobelko, K.I. Paper electrophoresis and x-ray structure study of the complex compounds of phenols with germanium. Russ Chem Bull 11, 31–37 (1962). https://doi.org/10.1007/BF00907482

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  • DOI: https://doi.org/10.1007/BF00907482

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