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Solubility of tetramethylammonium superoxide [(CH3)4N]O2 in liquid ammonia

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The solubility in the system [(CH3)4N]O2-NH3 was studied in a temperature interval of −35 °–−74°. The system is characterized by the presence of a simple eutectic at −79 ° at a concentration of ∼0.4 g of tetramethylammonium Superoxide per 100 g of liquid ammonia.

  2. 2.

    The solubility of tetramethylammonium Superoxide is in the vicinity of the boiling point of ammonia and amounts to ∼7g/100 g of NH3 at −35°.

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Literature cited

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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, p. 2074, September, 1969.

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Cherkasov, É.N., Tokareva, S.A. & Vol'nov, I.I. Solubility of tetramethylammonium superoxide [(CH3)4N]O2 in liquid ammonia. Russ Chem Bull 18, 1933–1934 (1969). https://doi.org/10.1007/BF00905852

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  • DOI: https://doi.org/10.1007/BF00905852

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