Conclusions
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1.
The methylated monosaccharides formed in the methylation of clematosides A′, A, and B have been separated and identified by gas-liquid chromatography.
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2.
The preparative isolation of the methylated monosaccharides has been carried out and their structures have been confirmed by chemical methods.
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3.
The structure of clematosides A′, A, and B has been discussed in the light of the results of methylation and periodate oxidation.
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Literature cited
V. Ya. Chirva and V. P. Konyukhov, Khimiya Prirodnykh Soedinenii, No. 2, 140 (1968).
V. Ya. Chirva and V. P. Konyukhov, Khimiya Prirodnykh Soedinenii, No. 2, 141 (1968).
A. J. Khorlin, V. J. Chirva, and N. K. Kochetkov, Tetrahedron Letters,1965, 2201.
A. Ya. Khorlin, V. Ya. Chirva, and N. K. Kochetkov, Izv. AN SSSR, Ser. Khim.,1966, 1963.
C. T. Bishop, Advances Carbohydr. Chenu,19, 95 (1964).
G. O. Aspinall, J. Chem. Soc.,1965, 1676.
J. Honeyman, J. Chem. Soc.,1940, 990.
J. T. Edward and D. M. Waldron, J. Chem. Soc.,1952, 3631.
J. K. N. Jones and J. H. S. Thomas, Can. J. Chem.,39, 192 (1961).
J. R. Dyer, Methods Biochem. Anal.,3, 111 (1954).
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2336–2340, October, 1968.
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Chirva, V.Y., Usov, A.N. & Konyukhov, V.P. Methylation and periodate oxidation of clematosides A', A, and B. Russ Chem Bull 17, 2204–2208 (1968). https://doi.org/10.1007/BF00904048
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DOI: https://doi.org/10.1007/BF00904048