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Reaction of furan and its derivatives with ethyl diazoacetate in the presence of copper sulfate

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

The thermocatalytic reaction of ethyl diazoacetate with alkylfurans and the esters of furylcarboxylic acids leads to the formation of the ethyl esters of the corresponding trans, trans 1, 3-alkadien-5-onecarboxylic acids, while reaction with furan leads to the formation of a mixture of a similar ester and 6-ethoxycarbonyl-2-oxabicyclo [3.1. 0]-3-hexene, which is easily isomerized to the former.

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Literature cited

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, USSR

    O. M. Nefedov, V. M. Shostakovskii, M. Ya. Samoilova & M. I. Kravchenko

Authors
  1. O. M. Nefedov
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  2. V. M. Shostakovskii
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  3. M. Ya. Samoilova
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  4. M. I. Kravchenko
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2342–2345, October, 1972.

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Nefedov, O.M., Shostakovskii, V.M., Samoilova, M.Y. et al. Reaction of furan and its derivatives with ethyl diazoacetate in the presence of copper sulfate. Russ Chem Bull 21, 2281–2284 (1972). https://doi.org/10.1007/BF00855322

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  • DOI: https://doi.org/10.1007/BF00855322

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