Conclusions
-
1.
A linear relationship was established between the NQR frequencies of Cl35 and chloroethanoanthracenes and the changes in the dipole moment of the C-Cl bond, predicted by the field effect theory.
-
2.
The cause of the anomalously high dipole moments of trans-disubstituted bicyclic molecules is not inductive interaction of the bonds.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
Literature cited
B. A. Arbuzov and A. N. Vereshchagin, Izv. Akad. Nauk SSSR, Ser. Khim., 1004 (1964).
B. A. Arbuzov. A, N. Vereshchagin, V. V. Karlin, and A. V. Aganov, Izv. Akad. Nauk SSSR, Ser. Khim., 1376 (1965).
B. A. Arbuzov and A. N. Vereshchagin, Izv. Akad. Nauk SSSR, Ser. Khim., 1731 (1966).
A. N. Vereshchagin and S. G. Vul'fson, Teoret. i Éksperim. Khimiya,1, 305 (1965)
A. N. Vereshchagin and S. G. Vul'fson, Izv. Akad. Nauk SSSR, Ser. Khim., 1226 (1967).
A. N. Vereshchagin, S. G. Vul'fson, and R. P. Arshinova, Izv. Akad. Nauk SSSR, Ser. Khim., 1459 (1967).
A. N. Vereshchagin and S. G. Vul'fson, Izv. Akad. Nauk SSSR, Ser. Khim., 1974 (1968).
J. W. Smith, Electric Dipole Moments, London (1955), p. 270.
G. K. Semin, T. A. Babushkina, and V. I. Robas, Zh. Fiz. Khimii,40, 2564 (1966).
Y. Morino, V. Miyagawa, T. Chiba, and T. Shimozawa, J. Chem. Phys.,25, 185 (1956).
G. K. Semin, Dokl. Akad. Nauk SSSR,158, 1169 (1964).
H. O. Hooper and P. J. Bray, J. Chem. Phys.,33, 334 (1960).
E. N. Tsvetkov, G. K. Semin, D. I. Lobanov, and M. I. Kabachnik, Dokl. Akad. Nauk SSSR,161, 1102 (1965).
I. P. Biryukov and M. G. Voronkov, Coll. Czechslov. Chem. Commun.,32, 830 (1968).
J. L. Musher, J. Chem. Phys.,37, 2372 (1962).
H. Shimizu and M. Shimizu, J. Chem. Phys.,40, 2068 (1964).
S. G. Vul'fson, I. P. Biryukov, and A. N. Vereshchagin, Izv. Akad. Nauk SSSR, Ser, Khim., 1008 (1970).
G. Del Re, J. Chem. Soc., 4031 (1958).
L. B. Kier, Tetrahedron Letters, 3273 (1965).
A. Remik, Electronic Concepts in Organic Chemistry [Russian translation], IL (1950), p. 88.
L. Bellamy, Infrared Spectra of Complex Molecules [Russian translation], IL (1963), p. 565.
J. Cantacuzene, J. Chim. Phys.,595, 186 (1962).
Author information
Authors and Affiliations
Additional information
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 6, pp. 1243–1247, June, 1970.
Rights and permissions
About this article
Cite this article
Arbuzov, B.A., Vulf'son, S.G., Safin, I.A. et al. Inductive interaction of the C-Cl bonds and nuclear quadrupole resonance spectra of Cl35 in chloro-substituted ethanoanthracenes. Russ Chem Bull 19, 1178–1181 (1970). https://doi.org/10.1007/BF00852654
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00852654