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Hydrophile Polymergele mit reaktiven Gruppen, 5. Mitt.: Chelatharze mit phosphorhaltigen Ankergruppen auf Basis von Saccharosemethacrylaten

Hydrophilic reactive polymer gels, part V: Chelating resins with phosphorus containing anchor groups based on sucrosemethacrylate gels

  • Organische Chemie Und Biochemie
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Abstract

Phosphorus containing chelating resins were synthesized by reaction of sucrosemethacrylate gels with various dialkylester halides of phosphoric acid and thiophosphoric acid. The sorption capacities of the hydrophilic gels were found to be max. 3.7 mmol/g and equilibrium was achieved within 5 minutes. The recycle of adsorption and elution was found to be satisfactory for Zn2+ and Cu2+ whereas only 50% of the bonded Hg2+ could be recovered reversibly.

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Authors and Affiliations

  1. Institut für chemische Technologie organischer Stoffe, Technische Universität Wien, A-1060, Wien, Österreich

    Heinrich Gruber & Norbert Gamsjäger

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  1. Heinrich Gruber
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  2. Norbert Gamsjäger
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Gruber, H., Gamsjäger, N. Hydrophile Polymergele mit reaktiven Gruppen, 5. Mitt.: Chelatharze mit phosphorhaltigen Ankergruppen auf Basis von Saccharosemethacrylaten. Monatsh Chem 115, 1329–1333 (1984). https://doi.org/10.1007/BF00798311

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  • DOI: https://doi.org/10.1007/BF00798311

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