Conclusions
Equations have been derived describing the growth kinetics of surface films. Conditions have been determined under which surface films cease to be porous and become coherent. Values of the coefficient of oxygen diffusion in copper at a temperature of 850°C calculated using the equations proposed and experimental data are in good agreement with a value cited in the literature.
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Ya. E. Geguzin, Physics of Sintering [in Russian], Nauka, Moscow (1967).
S. S. Kiparisov, L. Z. Rumshiskii, et al., “Influence of gases on the sintering of porous solids (Part I),” Poroshk. Metall., No. 12, 30–34 (1974).
Yu. V. Levinskii, Constitution Diagrams of Metals with Gases [in Russian], Metallurgiya, Moscow (1975).
F. N. Rhines, W. A. Johnson, and W. A. Anderson, “Rates of high-temperature oxidation of dilute copper alloys,” Trans. Am. Inst. Mining Met. Engr.,147, 205–216 (1952).
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Translated from Poroshkovaya Metallurgiya, No. 2(182), pp. 22–25, February, 1978.
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Levinskii, Y.V. Growth kinetics of a surface film during the annealing of a mixture of a metal powder and a decomposing oxide. Powder Metall Met Ceram 17, 103–106 (1978). https://doi.org/10.1007/BF00796336
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DOI: https://doi.org/10.1007/BF00796336