Abstract
Reduction of l-hydroxy-3-imidazoline-3-oxides with NaBH4 gives 1,3-dihydroxyimidazolidines. The latter on subsequent treatment with NH2OH · HCl in EtOH or in hydrochloric acid afford 1,2-bishydroxylamines. An X-ray study of 1,2-bishydroxylaminocycloalkanes has shown them to becis-configurated.
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Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 5, pp. 896–901, May, 1993.
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Mazhukin, D.G., Tikhonov, A.Y., Volodarskii, L.B. et al. Synthesis of aliphatic 1,2-bishydroxylamines from 1,3- dihydroxyimidazolidines.. Russ Chem Bull 42, 851–857 (1993). https://doi.org/10.1007/BF00698944
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DOI: https://doi.org/10.1007/BF00698944