Abstract
It is shown that, in the case of some halomethanes for which an Arrhenius-type relation can be fitted to the IRMPD probabilities as a function of CO2-laser pulse energy, the pre-exponential factor is about equal to the ratio of the reaction volume to the total gas volume.
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References
M. NèvedeMévergnies Infrared Phys.25, 175 (1985)
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See, e.g., S. Glasstone:Textbook of Physical Chemistry (Van Nostrand, New York (1958) pp. 1087–1111, and “Physical Chemistry”, Vol. VIB (“Kinetics of Gas Reactions”) ed. by W. Jost (Academic, New York 1975) pp. 864–866
I. P. Herman: Opt. Lett.4, 403 (1979)
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de Mévergnies, M.N. Remarks concerning the applicability of an Arrhenius-type relation to infrared multiphoton dissociation processes. Appl. Phys. B 43, 123–126 (1987). https://doi.org/10.1007/BF00692827
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DOI: https://doi.org/10.1007/BF00692827