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Vibrational spectra of crystalline potassium ferri- and ferrocyanide

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Abstract

The IR spectra of the crystalline salts K3[Fe(CN)6] (I) and K4[Fe(CN)6] (II) have been studied in the 1600–5000 cm−1 range for the purpose of investigating the spectral difference in the valence states of the central atoms of the complex anions. The appearance of the doublet structure of thev 6 band in the spectrum of salt II is due to distortion of its anion to D4h symmetry. The vibrational spectra of both salts are interpreted.

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Authors
  1. Yu. A. Klyuev
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Additional information

In conclusion, I should like to express ray sincere appreciation to Academician A. N. Terenin for his guidance and to L. A. Grivov and D. S, Bystrov for their valuable comments.

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Klyuev, Y.A. Vibrational spectra of crystalline potassium ferri- and ferrocyanide. J Appl Spectrosc 3, 30–34 (1965). https://doi.org/10.1007/BF00653885

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