Cyanopolyyne chemistry in TMC-1

Abstract

Using pseudo-time-dependent models and three different reaction networks, a detailed study of the dominant reaction pathways for the formation of cyanopolyynes and their abundances in TMC-1 is presented. The analysis of the chemical reactions show that for the formation of cyanopolyynes there are two major chemical regimes. First, early times of less than ∼10⁴ yrs when ion-molecule reactions are dominant, the main chemical route for the formation of larger cyanopolyynes is

$$C_n H^ + \xrightarrow{N}C_n N^ + \xrightarrow{{H_2 }}HC_n N^ + \xrightarrow{{H_2 }}H_2 C_n N^ + \xrightarrow{{e^ - }}HC_n N$$

wheren=5, 7, and 9. Second, at times greater than 10⁴ yrs, when neutral-neutral reactions become dominant, two major reaction routes for the formation of cyanopolyynes are (a),

$$HCN\xrightarrow{{C_2 H}}HC_3 N\xrightarrow{{C_2 H}}HC_5 N\xrightarrow{{C_2 H}}HC_7 N\xrightarrow{{C_2 H}}HC_9 N$$

and (b)

$$C_n H_2 + CN \to HC_{n + 1} N + H,{\text{ }}n = 4,6, and 8$$

depending on the reaction network used. The results indicate that for route (a) large abundances ofC ₂ H (fractional abundances of ∼10⁻⁷), and for route (b) large abundances ofC ₂ H ₂ are required in order to reproduce the observed abundances of cyanopolyynes. The calculated abundances of cyanopolyynes show great sensitivity to the value of extinction particularly att≳5×10⁵ yrs (i.e. photochemical timescale). The effect of other physical parameters, such as the cosmic-ray ionization abundances are also examined. In general, the model calculations show that the observed abundances of cyanopolyynes can be achieved by pseudo-time-dependent models at late times of several million years.