Abstract
The reaction of fluorine with copper and iron was studied within a very wide temperature and pressure range. Under medium fluorine pressures the formation of continuous films is observed. With low fluorine pressures and at relatively high temperatures a process of nucleation and growth of fluorides takes place. The presence of traces of oxygen in the gas phase can have a strong influence on the nature of the products formed.
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Gillardeau, J., Macheteau, Y., Plurien, P. et al. Some aspects of the fluoridation of copper and iron. Oxid Met 2, 319–330 (1970). https://doi.org/10.1007/BF00614624
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DOI: https://doi.org/10.1007/BF00614624