Abstract
Peculiar dendritic deposits of mercury were obtained galvanostatically from the mercurous nitratemethanol-water system at −50° C. These deposits could not be maintained at a constant shape because, when the current was interrupted, they transformed and shrank immediately to a spherical shape with hydrogen evolution. It seems that when the electrical potential was removed, the mercury deposits liquefied and the hydrogen stored in them was released during the period of shrinking.
Similar content being viewed by others
References
S. Tajima and M. Ogata,Electrochim. Acta 10 (1968) 1845.
Idem, ibid 15 (1970) 61.
M. Ogata, H. Kawaguchi and S. Tajima,Denkikagaku 38 (1970) 55.
S. Tajima, N. Baba and S. Morisaki,Electrochim. Acta 17 (1972) 833.
S. Tajima, S. Komatsu and N. Baba,ibid 19 (1974) 921.
S. Tajima, N. Baba and T. Midorikawa,J. Appl. Electrochem. 6 (1976) 243.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Tajima, S., Morisaki, S. & Shimizu, S. Electrodeposition of mercury from the HgNO3-CH3OH-H2O system at low temperature. J Appl Electrochem 11, 287–289 (1981). https://doi.org/10.1007/BF00613945
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00613945