Skip to main content
Log in

Withasteroids of Physalis. IX. Physangulide — The first natural 22S-withasteroid

  • Published:
Chemistry of Natural Compounds Aims and scope

Abstract

A new withasteroid — physangulide — has been isolated from the leaves ofPhysalis angulata L. It has been shown that physangulide is the first natural 22S-withanolide. Its structure has been determined as 3β,4β,20,24,25-pentahydroxy-1-oxo-5β,6β-epoxy-20R,22S,24S,25R-withanolide. Its1H and13C NMR spectra, confirming this interpretation, are given.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

Literature cited

  1. E. Glotter, M. Sahai, and I. Kirson, J. Chem. Soc., Perkin I, 2241 (1985).

  2. I. Kirson and E. Glotter, J. Nat. Prod.,44, No. 6, 633 (1981).

    Article  CAS  Google Scholar 

  3. K. L. Dhar and M. L. Raina, Phytochemistry,12, No. 12, 476 (1973).

    Article  CAS  Google Scholar 

  4. A. K. Kalla, M. L. Raina, K. L. Dhar, M. A. Qurishi, and G. Snatzke, Phytochemistry,18, No. 4, 637 (1979).

    Article  CAS  Google Scholar 

  5. O. E. Vasina, V. A. Maslennikova, N. D. Abdullaev, and N. K. Abibakirov, in: VIIIth Indo-Soviet Symposium on the Chemistry of Natural Products, 8–12 December, 1986, Hyderabad (India), Abstracts (Supplement), p. 33.

  6. I. Kirson, D. Lavie, S. M. Albonico, and H. R. Juliani, Tetrahedron,26, No. 21, 5063 (1970).

    Article  CAS  Google Scholar 

  7. S. W. Pelletier, G. Gebeychu, J. Nowacki, and N. V. Mody, Heterocycles,15, No. 1, 317 (1981).

    Article  CAS  Google Scholar 

  8. A. V. Kamernitskii, I. G. Reshetova, and V. A. Krivoruchko, Khim. Prir. Soedin., No. 2, 156 (1977).

  9. O. E. Vasina, V. A. Maslennikova, N. D. Abdullaev, and N. K. Abubakirov, Khim. Prir. Soedin., No. 5, 596 (1986).

  10. N. D. Abdullaev, O. E. Vasina, V. A. Maslennikova, and N. K. Abubakirov, Khim. Prir. Soedin, No. 3, 326 (1986).

  11. D. Lavie, Bol. Inst. Quim. Univ. Nacl. Auton. Max.,22, 181 (1970).

    CAS  Google Scholar 

  12. G. P. Moiseeva, O. E. Vasina, and N. K. Abubakirov, Khim. Prir. Soedin., 371 (1990) [following paper in this issue].

Download references

Authors

Additional information

Institute of the Chemistry of Plant Substances, Uzbek SSR Academy of Sciences, Tashkent. Translated from Khimiya Prirodnykh Soedinenii, No. 3, pp. 366–371, May–June, 1990.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Vasina, O.E., Abdullaev, N.D. & Abubakirov, N.K. Withasteroids of Physalis. IX. Physangulide — The first natural 22S-withasteroid. Chem Nat Compd 26, 304–307 (1990). https://doi.org/10.1007/BF00597855

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00597855

Keywords

Navigation