Skip to main content
Log in

Diamagnetic characterization of carbon fibres from pitch mesophase, pitch and polyacrylonitrile

  • Papers
  • Published:
Journal of Materials Science Aims and scope Submit manuscript

Abstract

The room temperature diamagnetic characteristics of carbon fibres from pitch mesophase (PM) have been determined and compared with those of fibres from isotropic pitch (P) and polyacrylonitrile (PAN) both in the as-processed condition and as a function of heat-treatment temperature over the approximate range 1000 to 3000° C. These fibre types show quite different magnetic behaviours indicative of different graphitizabilities which may be ranked PM, PAN, P in decreasing order. Microstructural and X-ray diffraction observations are also consistent with this ranking. Magnetic measurements provide a useful tool for characterization of fibre type and/or processing history.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. R. Bacon, in ″Chemistry and Physics of Carbon″, edited by P. L. Walker, Jun. and P. A. Thrower, Vol. 9 (Marcel Dekker, New York, 1973) pp. 1–102.

    Google Scholar 

  2. W. N. Reynolds,ibid″, Vol. 11 (1973) pp. 1–67.

    Google Scholar 

  3. H. F. Volk, ″Proceedings of the 4th London International Carbon and Graphite Conference, 1974, (Society of Chemical Industry, London, 1976) pp. 183–9.

    Google Scholar 

  4. R. Didchenko, J. B. Barr, S. Chwastiak, I. C. Lewis, R. T. Lewis andL. S. Singer, ″Extended Abstracts and Program″, 12th Biennial Conference on Carbon, Pittsburgh, July 1975, pp 329–32.

  5. J. B. Barr, S. Chwastiak, R. Didchenko, I. C. Lewis, R. T. Lewis andL. S. Singer,Appl. Polymer Symp. 29 (1976) 161.

    Google Scholar 

  6. J. B. Barr, S. Chwastiak andR. Didchenko, ″Extended Abstracts and Program, 13th Biennial Conference on Carbon, Irvine, California, July 1977, pp. 96–7.

  7. D. B. Fischbach, in ″Physics and Chemistry of Carbon″, Vol. 7, edited by P. L. Walker, Jun. (Marcel Dekker, New York, 1971) pp. 1–105.

    Google Scholar 

  8. C. B. Scott andD. B. Fischbach,J. Appl. Phys. 47 (1976) 5329–35.

    Google Scholar 

  9. G. B. Mellinger andD. B. Fischbach,″Extended Abstracts and Program″, 12th Biennial Conference on Carbon, Pittsburgh, July 1975, pp. 277–8.

  10. H. Volk, private communciation (1978).

  11. A. Pacault, in ″Chemistry and Physics of Carbon″, Vol. 7, edited by P. L. Walker, Jun. (Marcel Dekker, New York, 1971) pp. 107–54.

    Google Scholar 

  12. R. L. Beatty andD. B. Fischbach, ″Carbon '72 Preprints″ (International Carbon Conf., Baden-Baden), Arbeitskreis Kohlenstoff, Deutsche Keramische Gessellschaft (1972) pp. 127–9.

  13. R. L. Beatty, Tech. Rept. ORNL-TM-4504, Oak Ridge National Laboratory, Oak Ridge, Tennessee (1975).

  14. A. S. Kotosonov, V. S. Tverskoi andV. I. Frolov,Akad. Nauk SSSR, Proc. Phys. Chem. 211–213 (1973) 647–9; ″Proceedings of the 4th London International Carbon and Graphite Conference, 1974 (Society of Chemical Industry, London, 1976) pp. 508–9.

    Google Scholar 

  15. C. N. Tyson,J. Phys. D: Appl. Phys. 8 (1975) 749–58.

    Google Scholar 

  16. A. Marchand andJ. V. Zanchetta,Carbon 3 (1966) 483–91.

    Google Scholar 

  17. K. Noto, K. Saito, K. Kawamura andT. Tsuzuku,Japan J. Appl. Phys. 14 (1975) 480–6.

    Google Scholar 

  18. M. E. Rorabaugh, M.S. Thesis, University of Washington (1976).

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Fischbach, D.B., Gilbert, D.W. Diamagnetic characterization of carbon fibres from pitch mesophase, pitch and polyacrylonitrile. J Mater Sci 14, 1586–1592 (1979). https://doi.org/10.1007/BF00569278

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00569278

Keywords

Navigation