Abstract
The room temperature diamagnetic characteristics of carbon fibres from pitch mesophase (PM) have been determined and compared with those of fibres from isotropic pitch (P) and polyacrylonitrile (PAN) both in the as-processed condition and as a function of heat-treatment temperature over the approximate range 1000 to 3000° C. These fibre types show quite different magnetic behaviours indicative of different graphitizabilities which may be ranked PM, PAN, P in decreasing order. Microstructural and X-ray diffraction observations are also consistent with this ranking. Magnetic measurements provide a useful tool for characterization of fibre type and/or processing history.
Similar content being viewed by others
References
R. Bacon, in ″Chemistry and Physics of Carbon″, edited by P. L. Walker, Jun. and P. A. Thrower, Vol. 9 (Marcel Dekker, New York, 1973) pp. 1–102.
W. N. Reynolds,ibid″, Vol. 11 (1973) pp. 1–67.
H. F. Volk, ″Proceedings of the 4th London International Carbon and Graphite Conference, 1974, (Society of Chemical Industry, London, 1976) pp. 183–9.
R. Didchenko, J. B. Barr, S. Chwastiak, I. C. Lewis, R. T. Lewis andL. S. Singer, ″Extended Abstracts and Program″, 12th Biennial Conference on Carbon, Pittsburgh, July 1975, pp 329–32.
J. B. Barr, S. Chwastiak, R. Didchenko, I. C. Lewis, R. T. Lewis andL. S. Singer,Appl. Polymer Symp. 29 (1976) 161.
J. B. Barr, S. Chwastiak andR. Didchenko, ″Extended Abstracts and Program, 13th Biennial Conference on Carbon, Irvine, California, July 1977, pp. 96–7.
D. B. Fischbach, in ″Physics and Chemistry of Carbon″, Vol. 7, edited by P. L. Walker, Jun. (Marcel Dekker, New York, 1971) pp. 1–105.
C. B. Scott andD. B. Fischbach,J. Appl. Phys. 47 (1976) 5329–35.
G. B. Mellinger andD. B. Fischbach,″Extended Abstracts and Program″, 12th Biennial Conference on Carbon, Pittsburgh, July 1975, pp. 277–8.
H. Volk, private communciation (1978).
A. Pacault, in ″Chemistry and Physics of Carbon″, Vol. 7, edited by P. L. Walker, Jun. (Marcel Dekker, New York, 1971) pp. 107–54.
R. L. Beatty andD. B. Fischbach, ″Carbon '72 Preprints″ (International Carbon Conf., Baden-Baden), Arbeitskreis Kohlenstoff, Deutsche Keramische Gessellschaft (1972) pp. 127–9.
R. L. Beatty, Tech. Rept. ORNL-TM-4504, Oak Ridge National Laboratory, Oak Ridge, Tennessee (1975).
A. S. Kotosonov, V. S. Tverskoi andV. I. Frolov,Akad. Nauk SSSR, Proc. Phys. Chem. 211–213 (1973) 647–9; ″Proceedings of the 4th London International Carbon and Graphite Conference, 1974 (Society of Chemical Industry, London, 1976) pp. 508–9.
C. N. Tyson,J. Phys. D: Appl. Phys. 8 (1975) 749–58.
A. Marchand andJ. V. Zanchetta,Carbon 3 (1966) 483–91.
K. Noto, K. Saito, K. Kawamura andT. Tsuzuku,Japan J. Appl. Phys. 14 (1975) 480–6.
M. E. Rorabaugh, M.S. Thesis, University of Washington (1976).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Fischbach, D.B., Gilbert, D.W. Diamagnetic characterization of carbon fibres from pitch mesophase, pitch and polyacrylonitrile. J Mater Sci 14, 1586–1592 (1979). https://doi.org/10.1007/BF00569278
Received:
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/BF00569278