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Infrared spectra of cyclic hexapeptides constructed of L(D)-alanine and glycine residues

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Chemistry of Natural Compounds Aims and scope

Summary

By IR spectroscopy in the middle and far regions of the spectrum it has been found that on being heated with KBr a number of cyclic hexapeptides with L(D)-alanine and glycine residues undergo a transition from a mixture of various conformers into a monotypical conformational state corresponding to the “pleated sheet” structure with two trans-annular hydrogen bonds of the 4 → 1 type.

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Authors
  1. G. A. Kogan
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  2. V. M. Tul'chinskii
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  3. V. V. Shilin
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  4. V. T. Ivanov
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Additional information

M. M. Shemyakin Institute of the Chemistry of Natural Compounds, Academy of Sciences of the USSR. Translated from Khimiya Prirodnykh Soedinenii, No. 3, pp. 361–369, May–June, 1972.

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Kogan, G.A., Tul'chinskii, V.M., Shilin, V.V. et al. Infrared spectra of cyclic hexapeptides constructed of L(D)-alanine and glycine residues. Chem Nat Compd 8, 353–359 (1972). https://doi.org/10.1007/BF00563748

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  • DOI: https://doi.org/10.1007/BF00563748

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