Abstract
Thermoluminescent (TL) mechanisms involving Fe, Cr, Mn and V ions in both divalent and trivalent valence states, and V-type centres were studied in MgO single crystals of varying impurity content after exposure to ultraviolet radiation. Using the ESR technique, it is shown that samples containing primarily divalent impurities show no V-type centres related to the TL mechanism, which is that of charge transfer between the impurities. V-type centres, when present, are seen to be more stable in purer samples than in less pure samples, resulting in a shift of the TL peaks to higher temperatures. The TL mechanism in this case includes charge transfer between V-type centres and the impurities. The supralinear behaviour of TL peak 1 is associated with the R-emission lines of Cr3+.
Similar content being viewed by others
References
J. E. Wertz, L. C. Hall, J. Hegelson, C. C. Chao and W. S. Dykoski, in “Interaction of Radiation with Solids”, edited by A. Bishay (Plenum Press, New York, 1967) p. 617.
K. H. Lee and J. H. Crawford, Jr, J. Lumin. 20 (1979) 9.
J. E. Wertz, J. W. Orton and P. Auzins, J. Appl. Phys. Suppl. 33 (1962) 322.
Y. Kirsh, N. Kristianpoller and R. Chen, Phil. Mag. 35 (1977) 653.
Y. Chen and W. A. Sibley, Phys. Rev. 154 (1967) 842.
A. Sathyamoorthy and J. M. Luthra, J. Mater Sci. 13 (1978) 2637.
N. Takeuchi, K. Inabe, J. Yamashita and S. Nakamura, Health Phys. 31 (1976) 519.
A. K. Dhar, L. A. DeWerd and T. G. Stoebe, Med Phys. 3 (1976) 415.
N. Takeuchi, K. Inabe and J. Yamashita, Phys. Chem. 259 (1978) 321.
W. M. Ziniker, J. K. Merrow and J. I. Mueller, J. Phys. Chem. Sol. 33 (1972) 1619.
C. S. Krishnan, PhD Thesis, University of Washington (1973).
F. A. Modine, E. Sonder and R. A. Weeks, J. Appl. Phys. 48 (1977) 3514.
K. W. Blazey, J. Phys. Chem. Sol. 38 (1977) 671.
J. B. Lacy, M. M. Abraham, J. L. Boldu, Y. Chen, J. Narayan and H. T. Tohver, Phys. Rev. B 18 (1978) 4136.
J. E. Wertz, P. Auzins, J. H. E. Griffiths and J. W. Orton, Disc. Far. Soc. 26 (1958) 66.
R. W. Davidge, J. Mater. Sci. 2 (1967) 339.
E. Sonder and W. A. Sibley, in “Point Defects in Solids” Vol. 1, edited by J. H. Crawford and L. M. Slifkin (Plenum Press, New York, 1972).
Y. Chen, M. M. Abraham, L. C. Templeton and W. P. Unruh, Phys. Rev. B 11 (1975) 881.
M. M. Abraham, Y. Chen and W. P. Unruh, ibid 9 (1974) 1842.
L. A. Kappers, F. Dravnieks and J. E. Wertz, Sol. Stat. Commun. 10 (1972) 1265.
W. P. Unruh, Y. Chen and M. M. Abrahan, Phys. Rev. Lett. 30 (1973) 446.
L. A. Kappers, F. Dravnieks and J. E. Wertz, J. Phys. C: Sol. St. Phys. 7 (1974) 1387.
B. Henderson, J. E. Wertz, J. P. Hall and R. D. Dowsing, ibid. 4 (1971) 107.
J. E. Wertz and P. Auzins, Phys. Rev. 106 1957) 484.
A. M. Glass and T. M. Searle, J. Chem. Phys. 46 (1967) 2092.
B. Henderson and W. A. Sibley, ibid 55 (1971) 1276.
E. R. Vance and W. C. Mallard, Phys. Stat. Sol. (b) 91 (1979) K155.
R. L. Hansler and W. G. Segelken, J. Phys. Chem. Sol. 13 (1960) 124.
R. A. Weeks, E. Sonder, J. C. Pigg and K. F. Kelton, J. Phys. (France) 37 (1976) C7–411.
L. J. Challis, A. A. Ghazi and K. J. Maxwell, J. Phys. C: Sol. St. Phys. 12 (1979) 303.
W. A. Sibley, J. L. Kolopus and W. C. Mallard, Phys. Stat. Sol. 31 (1969) 223.
W. C. Las, R. J. Matthews and T. G. Stoebe, Nucl. Inst. Methods 175 (1980) 1.
R. T. Williams, J. W. Williams, T. J. Turner and K. H. Lee, Phys. Rev. B 20 (1979) 1687.
S. Datta, I. M. Boswarva and D. B. Holt, J. Phys. Chem. Solids 40 (1979) 567.
D. B. Holt, S. Datta and I. M. Boswarva, J. Phys. (France) 41 (1980) C6–522.
N. Takeuchi, K. Inabe and H. Nanto, Phys. Stat. Sol. (a) 33 (1976) K125.
W. C. Las and T. G. Stoebe, J. Mater. Sci. 16 (1981) 1191.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Las, W.C., Stoebe, T.G. Thermoluminescent mechanisms involving transition metal ion impurities and V-type centres in MgO crystals exposed to ultraviolet radiation. J Mater Sci 17, 2585–2593 (1982). https://doi.org/10.1007/BF00543891
Received:
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/BF00543891