Abstract
Depending on the pH of the medium, when 2-formylquinoxaline hydrate N,N′-dioxide is subjected to attack by the OH− anion, it undergoes redox transformations to give 2-carboxyquinoxaline 4-oxide or quinoline N,N′-dioxide and the formate ion. In the case of attack by the OH− anion 2-formylquinoxaline diethylacetal N,N′-dioxide undergoes only the first reaction, regardless of the pH.
Similar content being viewed by others
Literature cited
W. S. Chilton and A. K. Butler, J. Org. Chem., 32, 1270 (1967).
A. S. Elina, L. G. Tsyrul'nikov, and G. P. Syrova, Khim. Geterotsikl. Soedin., No. 2, 149 (1969).
C. W. Much, J. C. Patton, B. Bhattacharya, D. L. Giberson, and C. A. Ferguson, J. Heterocycl. Chem., 9, 1299 (1972).
A. S. Elina, I. S. Musatova, and G. P. Syrova, Khim. Geterotsikl. Soedin., No. 9, 1275 (1972).
R. M. Titkova, A. S. Elina, E. A. Trifonova, and T. A. Gus'kova, Khim. Farm. Zh., 6, 81 (1978).
A. S. Elina and O. Yu. Magidson, Zh. Obshch. Khim., 25, 161 (1955).
J. K. Landquist, J. Chem. Soc., 2816 (1953).
Author information
Authors and Affiliations
Additional information
Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 8, pp. 1106–1108, August, 1980.
Rights and permissions
About this article
Cite this article
Elina, A.S., Musatova, I.S., Titkova, R.M. et al. Redox transformations of 2-formylquinoxaline hydrate and diethylacetal N,N′-dioxides. Chem Heterocycl Compd 16, 861–863 (1980). https://doi.org/10.1007/BF00513172
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00513172