Abstract
This work reviews and discusses the data and information on the various thermodynamic properties of vanadium available through March 1985. These include the heat capacity and enthalpy, enthalpy of melting, vapor pressure, and enthalpy of vaporization. The existing data have been critically evaluated and analyzed, and the recommended values for heat capacity, enthalpy, entropy, and Gibbs energy function covering the temperature range from 1 to 3800 K have been generated. These values are referred to temperatures based on IPTS-1968. The units used for various properties are joules per mole (J · mol−1). The estimated uncertainties in the heat capacity are ±3% below 15 K, ±10% from 15 to 150 K, ±3% from 150 to 298.15 K, ±2% from 298.15 to 1000 K, ±3% from 1000 to the melting point (2202 K), and ±5% in the liquid region.
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H. A. Leupold, G. J. Iafrate, F. Rothwarf, J. T. Breslin, D. Edmiston, and T. R. AuCoin, J. Low Temp. Phys. 28:241 (1977).
P. H. Keesom and R. Radebaugh, Phys. Rev. Lett. 13:685 (1964).
E. Rudy, Compendium of Phase Diagram Data, U.S. Air Force Rep. AFML-TR-65-2, Pt. IV (1969).
J. L. Margrave, Mater. Res. Soc. Symp. Proc. 9:39 (1982).
G. R. Gathers, J. W. Shaner, R. S. Hixson, and D. A. Young, High Temp. High Press. 11:653 (1979).
R. Radebaugh, Ph.D. thesis (Purdue University, West Lafayette, Ind., 1966). (PU-66-13248).
W. S. Corak, B. B. Goodman, C. B. Satterthwaite, and A. Wexler, Phys. Rev. 96:1442 (1954).
W. S. Corak, B. B. Goodman, C. B. Satterthwaite, and A. Wexler, Phys. Rev. 102:656 (1956).
G. J. Sellers, M. Paalanen, and A. C. Anderson, Phys. Rev. 10:1912 (1974).
N. A. Chernoplekov, G. Kh. Panova, B. N. Samoilov, and A. A. Shikov, Zh. Eksp. Teor. Fiz. 63:1381 (1972); English translation, Sov. Phys. JETP 36:731 (1973).
M. Ishikawa, Ph.D. thesis (University of Minnesota, Minneapolis, 1971). (UM-71-22213).
C. H. Cheng, K. P. Gupta, E. C. Van Reuth, and P. A. Beck, Phys. Rev. 126:2030 (1962).
Y. I. Shen, Ph.D. thesis (University of California, Berkeley, 1965). (UCRL-16117).
R. D. Worley, M. W. Zemansky, and H. A. Boorse, Phys. Rev. 99:447 (1955).
E. C. Van Reuth, Ph.D. thesis (University of Illinois, Urbana, 1964). (UI-64-8451).
V. M. Pan, V. G. Prokhorov, A. D. Shevchenko, and V. P. Dovgopol, Fiz. Nizk. Temp. (Kiev) 3:1266 (1977); English translation, Sov. J. Low Temp. Phys. 3:609 (1977).
D. Ohlendorf and E. Wicke, J. Phys. Chem. Solids 40:721 (1979).
Y. Takahashi, J. Nakamura, and J. F. Smith, J. Chem. Thermodynam. 14:977 (1982).
K. Kumagai and T. Ohtsuka, J. Phys. Soc. Jpn. 37:384 (1974).
J. M. Corsan and A. J. Cook, Phys. Status Solidi 40:657 (1970).
A. Junod, F. Heiniger, J. Mueller, and P. Spitzli, Helv. Phys. Acta 43:59 (1970).
D. D. Martin, M.S. thesis (Southern Methodist University, Dallas, Tex., 1963).
G. H. Comsa, D. Heitkamp, and H. S. Raede, Solid State Commun. 20:877 (1976).
O. Vergara, D. Heitkamp, and H. V. Lohneysen, J. Phys. Chem. Solids 45:251 (1984).
R. Radebaugh and P. H. Keesom, Phys. Rev. 149:209 (1966).
N. A. Chernoplekov, G. Kh. Panova, B. N. Samoilov, and A. A. Shikov, Zh. Eksp. Teor. Fiz. 64:195 (1973); English translation, Sov. Phys. JETP 37:102 (1973).
Y. Takahashi, J. Nakamura, H. Akiyama, and T. Azumi, Proc. Jap. Symp. Thermophys. Prop, 1st, 93–6 (1980).
C. T. Anderson, J. Am. Chem. Soc. 58:564 (1936).
Z. Bieganski and B. Stalinski, Bull. Acad. Polon. Sci. Ser. Sci. Chim. 9:367 (1961).
K. Clusius, P. Franzosini, and U. Piesbergen, Z. Naturforsch. 15A:728 (1960).
R. Hultgren, P. D. Desai, D. T. Hawkins, M. Gleiser, K. K. Kelley, and D. D. Wagman, Selected Values of the Thermodynamic Properties of the Elements (American Society for Metals, Metals Park, Ohio, 1973).
A. Cezairliyan, F. Righini, and J. L. McClure, U.S. Air Force Rep. AFOSR-TR-75-0596, 30-46 (1974). (AD A008 935)
J. L. Margrave, Rice Univ. Rep. ORO-2907-92 (1972).
B. Ya. Berezin and V. Ya. Chekhovskoi, Teplofiz. Vys. Temp. 15:772 (1977); English translation, High Temp. 15:651 (1977).
V. Ya. Chekhovskoi and R. G. Kalinkina, Teplofiz. Vys. Temp. 11:885 (1973); English translation, High Temp. 11:796 (1973).
W. Bendick and W. Pepperhoff, J. Phys. F 12:1085 (1982).
R. A. Knezek, M.S. thesis (Oklahoma State University, Stillwater, 1959).
A. V. Arutyunov, I. N. Makarenko, and L. P. Filippov, Teplofiz. Svoistva Veshchestv Mater. 5:105 (1972).
V. E. Peletskii, V. P. Druzhinin, and Ya. G. Sobol, High Temp. High Press. 3:153 (1971).
R. Kohlhaas, M. Braun, and O. Vollmer, Z. Naturforsch. 20A:1077 (1965).
M. Braun, R. Kohlhaas, and O. Vollmer, Z. Angew. Phys. 25:365 (1968).
G. C. Beakley, Jr., Ph.D. thesis (Oklahoma State University, Stillwater, 1956).
Yu. M. Golutvin and T. M. Kozlovskaya, Zh. Fiz. Khim. 36:362 (1962); English translation, Russ. J. Phys. Chem. 36:183 (1962).
L. P. Filippov, Int. J. Heat Mass Transfer 16:865 (1973).
L. P. Filippov, L. N. Trukhanova, I. N. Makarenko, and A. V. Arutyunov, Teplofiz. Svoistva Tverd. Veshchestv, Mater. Vses. Teplofiz. Konf. Svoistvam Veshchestv Vys. Temp, 4th, 51–6 (1971).
B. E. Neimark, P. E. Belyakova, B. R. Brodskii, L. K. Voronin, S. F. Korytina, and A. N. Merkul'ev, Heat Transfer Sov. Res. 5:141 (1973).
F. M. Jaeger and W. A. Veenstra, Proc. K Akad. Wet. Amsterdam 37:61 (1934).
F. M. Jaeger and W. A. Veenstra, Rec. Trav. Chim. 53:677 (1934).
I. B. Fieldhouse and J. I. Lang, U.S. Air Force Rep. WADD-TR-60-940 (1961). (AD 268 304)
B. Ya. Berezin, V. Ya. Chekhovskoi, and A. E. Sheindlin, High Temp. Sci. 4:478 (1972).
J. A. Treverton and J. L. Margrave, J. Chem. Thermodyn. 3:473 (1971).
J. F. Smith, Bull. Alloy Phase Diag. 2:40 (1981).
V. P. Glushko, L. V. Gurvich, G. A. Bergman, I. V. Veitz, V. A. Medvedev, G. A. Khachkuruzov, and V. S. Yungman, Thermodynamic Properties of Individual Substances, Vol. IV (High-Temperature Institute of Applied Chemistry, National Academy of Sciences of the USSR, Moscow, 1982).
M. W. Chase, Private communications (Thermal Lab., Dow Chemical USA, Midland, Tex., 1985).
R. K. Saxer, Ph.D. thesis (Ohio State University, Columbus, 1962).
J. W. Edwards, H. L. Johnstone, and P. E. Blackburn, J. Am. Chem. Soc. 73:4727 (1951).
R. H. Moore, D. Robinson, and B. B. Argent, J. Phys. E 8:641 (1975).
M. Farber and R. D. Srivastava, J. Chem. Soc. Faraday Trans. 69:390 (1973).
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Desai, P.D. Thermodynamic properties of vanadium. Int J Thermophys 7, 213–228 (1986). https://doi.org/10.1007/BF00503812
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DOI: https://doi.org/10.1007/BF00503812