Summary
Multicomponent analysis often suffers from matrix effects. In the present paper several methods are employed to cope with those effects and to keep experimental expense as low as possible and hence to reduce analysis time. Based on the determination of Na, K, and Ca by flame atomic emission spectroscopy experimental design in combination with multivariate calibration (matrix methods) has been tested for suitability in multicomponent analysis. Good results are achieved by statistically designed experiments. The experimental domain should be kept small to allow for linear models. Comparable results are obtained using the P method. As expected the K approach (Beer model) yields the worst results.
Similar content being viewed by others
Literatur
Parczewski A, Koscielniak P (1979) Fresenius Z Anal Chem 297:148
Koscielniak P, Parczewski A, Walas S (1979) Fresenius Z Anal Chem 297:156
Koscielniak P, Parczewski A (1983) Anal Chim Acta 153:111
Koscielniak P, Parczewski A (1984) Chem Anal 29:685
Scheffler E (1973) Einführung in die Praxis der statistischen Versuchsplanung. Verlag für Grundstoffindustrie, Leipzig
Retzlaff G, Waibel J (1978) Statistische Versuchsplanung. Verlag Chemie, Weinheim New York
Brown CW, Lynch PF, Obremski RJ, Lavery DS (1982) Anal Chem 54:1472
Maris MA, Brown CW, Lavery DS (1983) Anal Chem 55:1694
Kisner HJ, Brown CW (1982) Anal Chem 54:1479
Weber K (1983) GIT Fachz Lab 27:937
Otto M, Wegscheider W (1985) Anal Chem 57:63
Opfermann J (1984) Programm zur nichtlinearen Ausgleichsrechnung für MC 80, FSU Jena, Sektion Chemie
Lawson CH, Hanson RJ (1974) Solving least squares problems. Prentice Hall Inc., Englewood Cliffs, NJ
Caulcutt R, Boddy R (1983) Statistics for analytical chemists. Chapman and Hall, London
Mitchell DG, Garden JS (1982) Talanta 29:291
Kalivas JH, Kowalski B (1982) Anal Chem 54:560
Lorber A, Goldbart Z, Harel A (1985) Anal Chem 57:2537
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Zwanziger, H., Steinführer, A., Werner, G. et al. Kombination von optimaler Versuchsplanung und einigen Matrixmethoden zur Mehrkomponentenkalibrierung und — analyse. Z. Anal. Chem. 330, 478–483 (1988). https://doi.org/10.1007/BF00490753
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1007/BF00490753