Skip to main content
SpringerLink
Log in

Electrochemical behaviour of N-methylene bridges in amino resin oligocondensation products

Über das elektrochemische Verhalten von N-Methylenbrücken in Aminoharzoligokondensaten

  • Original Papers
  • Published:
Fresenius' Zeitschrift für analytische Chemie Aims and scope Submit manuscript

Zusammenfassung

N-Methylenbrücken in Aminoharzoligokondensaten lassen sich mittels einer selektiven polarographischen Methode mit guter Genauigkeit bestimmen. Aus den Untersuchungen zum elektrochemischen Reaktionsmechanismus geht hervor, daß N-Methylenbrückenstrukturen eine katalytische Wasserstoffwelle verursachen, die auf Grund ihrer guten Konzentrationsproportionalität zu analytischen Bestimmungen herangezogen werden kann. Untersuchungen an Anilin-, Harnstoff-, Hexahydrotriazin- und Acrylamidverbindungen bestätigen den Mechanismus und weisen auf die Möglichkeit einer breiteren Nutzung der Methode hin.

Summary

N-methylene bridges in amino resin oligocondensation products can be determined with sufficient reliability by a selective polarographic method. By investigating the mechanism of the electrochemical reaction the methylene bridges were found to cause a catalytic hydrogen wave which, due to its proportionality to the concentration, provides the basis for the analytical determination. The results obtained with aniline, urea, hexahydrotriazine and acrylamide support this mechanism and suggest further possibilities of application of this method.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

References

  1. Nastke R, Dietrich K, Rafler G, Reinisch G, to be published

  2. Herma H, Dietrich K, Schilling B (1983) Plaste u Kautschuk 30:132–200

    CAS  Google Scholar 

  3. Growe GA, Lych CR (1950) J Am Chem Soc 72:3622

    Article  Google Scholar 

  4. Landquist N (1955) Acta Chem Scand 9: 1127

    Article  Google Scholar 

  5. Nastke R, Dietrich K, Teige W (1979) Acta Polymerica 30:522

    Article  Google Scholar 

  6. Nastke R (1983) Diss Akad Wiss DDR

  7. Zuman P (1969) Elucidation of organic electrode processes. Acad Press, New York

    Google Scholar 

  8. Heyrovsky J, Kuta J (1965) Grundlagen der Polarographie. Akad Vlg Berlin, S 377–400

  9. Brown ER, Large RF (1971) Phys Methoden der Org Chemie, Tl 2. Wiley, New York

    Google Scholar 

  10. Kadowaki H (1936) Bull Chem Soc Japan 11:248

    Article  CAS  Google Scholar 

  11. Ulrich HH (1970) Diss Friedrich-Schiller-Universität Jena

Download references

Author information

Authors and Affiliations

  1. Institut für Polymerenchemie „Erich Correns“, Akademie der Wissenschaften der DDR, DDR-1530, Teltow-Seehof

    R. Nastke & K. Dietrich

  2. Sektion Chemie, Humboldt-Universität zu Berlin, Hessische Straße 1-2, DDR-1040, Berlin, German Democratic Republic

    F. Pragst

Authors
  1. R. Nastke
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. K. Dietrich
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. F. Pragst
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Nastke, R., Dietrich, K. & Pragst, F. Electrochemical behaviour of N-methylene bridges in amino resin oligocondensation products. Z. Anal. Chem. 319, 252–254 (1984). https://doi.org/10.1007/BF00487267

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00487267

Keywords

Search

Navigation