Abstract
A study was made of the mechanism of the reaction between N-chloramines and 2-mercapto benzthiazole in water and in inert solvents. It was shown that in water and alcohol, in addition to the formation of sulfenamides, there is an oxidation reaction of 2-mercapto benzthiazole by hypochlorous acid to the disulfide.
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References
V. A. Ignatov, P. A. Pirogov, and M. S. Fel'dshtein, ZhOrKh, 4, 2025, 1968.
K. K. Ingold, Mechanism of Reactions and Structure of Organic Compounds [Russian translation], IL, Moscow, 279, 1959.
B. V. Nekrasov, A Course in General Chemistry [in Russian], GKhI, Moscow-Leningrad, 349, 1954.
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Ignatov, V.A., Pirogov, P.A. A study of the formation reactions of amides of 2-benzthiazolylsulphenic acid from N-chloramines and 2-mercapto benzthiazone. Chem Heterocycl Compd 6, 85–88 (1970). https://doi.org/10.1007/BF00475432
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DOI: https://doi.org/10.1007/BF00475432