Abstract
A review is presented on elegant procedures, which allow to arrive at large enrichments of optical antipodes through solid-phase reactions. The basic molecular mechanisms that have been discussed in literature already 100 years ago have been thoroughly investigated and described only recently and are of equal importance both from the purely scientific and the industrial application viewpoint.
Similar content being viewed by others
references
Van't Hoff, J.H., Dawson, T.H.: Ber. dtsch. Chem. Ges. 31, 528 (1898)
Kipping, F.S., Pope, W.J.: J. Chem. Soc. 95, 103 (1903)
Ostromisslensky, J.: Chem. Ber. 41, 3035 (1908)
Havinga, E.: Chem. Weekbl. 38, 642 (1941); Biochim. Biophys. Acta 13, 171 (1954)
Penzien, U., Schmidt, G.M.J.: Angew. Chem. Int. Ed. Engl. 8, 608 (1969)
Schmidt, G.M.J.: Pure Appl. Chem. 27, 647 (1971)
Rabinovich, D., Schmidt, G.M.J.: Nature 211, 1391 (1966)
Kitaigorodsky, D.I.: Molecular Crystals and Molecules, p. 33, New York: Academic Press 1973
Leiserowitz, L., Schmidt, G.M.J.: J. Chem. Soc. A 1969, 2372
Collet, A., Jaques, J.: Bull. Soc. Chim. Fr. 1972, 3700
Green, B.S., Zitat nach: Green, B.S., Lahav, M., Rabinovich, D.: Acc. Chem. Res. 12, 191 (1979)
Pincock, R.E., et al.: Science 174 1018 (1971)
Pincock, R.E., Bradshaw, R.P., Perkins, R.R.: J. Mol. Evol. 4, 67 (1974); Wilson, K.R., Pincock, R.E.: J. Am. Chem. Soc. 97, 1474 (1975)
Green, B.S., Lahav, M.: J. Mol. Evol. 6, 99 (1975); Addadi, L., Lahav, M.: J. Am. Chem. Soc. 100, 2838 (1978); 101, 2152 (1979); Pure Appl. Chem. 51, 1269 (1979); Addadi, L., et al.: Origins Life 11, 107 (1981)
Farina, M.: Proc. Int. Symp. Macromolecules, Rio de Janeiro 1974, p. 21; Farina, M., Andisio, G., Natta, G.: J. Am. Chem. Soc. 89, 5071 (1967)
Lahav, M., et al.: ibid. 98, 1620 (1976)
Cairns-Smith, P.G.: The Life Puzzle. Edinburgh: Oliver & Boyd 1971
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Thiemann, W. Schmelzen und optische Aktivität. Naturwissenschaften 69, 123–129 (1982). https://doi.org/10.1007/BF00376716
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00376716