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The effect of water, pressure, and strain on Al/Si order-disorder kinetics in feldspar

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Abstract

The disordering kinetics of Al/Si in albite depend on how the samples are dried, and thus on the presence of trace amounts of water. The disordering rate increases with water content and confining pressure. At 10 kb the activation energy is about 67 kcal/mole compared to about 87 kcal/mole for samples disordered in air. Simultaneous plastic deformation increases the disordering rate and the effect is most pronounced below 900° C at 10−6/s. Some albite ordering and microcline disordering experiments show similar kinetic behavior. These results are significant for interpreting the structural state and the high-temperature deformation of feldspars.

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References

  • Cohen, M.: Self-diffusion during plastic deformation. Trans. Jpn. Inst. Met. 11, 145–151 (1970)

    Google Scholar 

  • Donnay, G., Wyart, J., Sabatier, G.: Structural mechanism of thermal and compositional transformation in silicates. Z. Kristallogr. Mineral. 112, 161–169 (1959)

    Google Scholar 

  • Goldsmith, J.R., Newton, R.C.: An experimental determination of the alkali feldspar solvus. In: The Feldspars (W.S. MacKenzie and J. Zussman, eds.), pp. 337–359. Great Britain: Manchester University Press 1974

    Google Scholar 

  • Guidotti, C.V., Herd, H.H., Tuttle, C.L.: Composition and structural state of K-feldspars from K-feldspar plus sillimanite grade rocks in northwestern Maine. Am. Mineral. 58, 705–716 (1973)

    Google Scholar 

  • Mason, R. A.: The ordering behavior of albite in aqueous solutions at 1 kbar. Contrib. Mineral. Petrol. 68, 269–273 (1979)

    Google Scholar 

  • McConnell, J.D.C., McKie, D.: The kinetics of the ordering process in triclinic NaAlSi3O8. Mineral. Mag. 32, 436–454 (1960)

    Google Scholar 

  • McKie, D., McConnell, J.D.C.: The kinetics of the low-high transformation in albite, I. Amelia albite under dry conditions. Mineral. Mag. 33, 581–588 (1963)

    Google Scholar 

  • Müller, G.: Der Ordnungs-Unordnungs-Übergang in getemperten Mikroklinen und Albiten. Z. Kristallogr. Mineral. 132, 212–227 (1970)

    Google Scholar 

  • Parsons, J.: Feldspars and fluid in cooling plutons. Mineral. Mag. 42, 1–18 (1978)

    Google Scholar 

  • Petrović, R., Skinner, B.J.: Alkali ion reaction between alkali feldspars and hydrothermal solutions: replacement vs. cation exchange. Geol. Soc. Am., Abs. with Progs. 669 (1971)

  • Raase, P.: The potassic feldspar in metamorphic rocks from the western Hohe Tauern area, eastern Alps. Geol. Rundsch. 65, 422–436 (1976)

    Google Scholar 

  • Seifert, K.E.: Rapid structural state conversion in intermediate composition plagioclase. Contrib. Mineral. Petrol. 41, 53–56 (1973)

    Google Scholar 

  • Sipling, P.J., Yund, R.A.: Kinetics of Al/Si disordering in alkali feldspars. In: Geochemical Transport and Kinetics (A.W. Hofmann, B.J. Giletti, H.S. Yoder, and R.A. Yund, eds.), pp. 185–193. New York: Academic Press 1974

    Google Scholar 

  • Smith, J.V.: Critical review of synthesis and occurrence of plagioclase feldspars and a possible phase diagram. J. Geol. 80, 505–525 (1972)

    Google Scholar 

  • Tullis, J., Yund, R.A.: Experimental deformation of dry Westerly granite. J. Geophys. Res. 82, 5707–5718 (1977)

    Google Scholar 

  • Tullis, J., Yund, R.A.: Hydrolytic weakening of experimentally deformed Westerly granite and Hale albite rock. J. Struct. Geol. (in press)

  • Voll, G.: Recrystallization of quartz, biotite and feldspars from Erstfeld to the Leventina Nappe, Swiss Alps, and its geological significance. Schweiz. Mineral. Petrogr. Mitt. 56, 641–647 (1976)

    Google Scholar 

  • Wilson, J.R., Coates, J.S.: Alkali feldspars from part of the Galway granite, Ireland. Mineral. Mag. 38, 801–810 (1972)

    Google Scholar 

  • Yund, R.A., Anderson, T.F.: Oxygen isotope exchange between potassium feldspar and KCl solution. In: Geochemical Transport and Kinetics (A.W. Hofmann, B.J. Giletti, H.S. Yoder, and R.A. Yund, eds.), pp. 99–105. New York: Academic Press 1974

    Google Scholar 

  • Yund, R.A., Anderson, T.F.: Oxygen isotope exchange between feldspar and fluid as a function of fluid pressure. Geochim. Cosmochim. Acta 42, 235–239 (1978)

    Google Scholar 

  • Yund, R.A., Davidson, P.: Kinetics of lamellar coarsening in cryptoperthites. Am. Mineral. 63, 470–477 (1978)

    Google Scholar 

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Yund, R.A., Tullis, J. The effect of water, pressure, and strain on Al/Si order-disorder kinetics in feldspar. Contr. Mineral. and Petrol. 72, 297–302 (1980). https://doi.org/10.1007/BF00376148

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  • DOI: https://doi.org/10.1007/BF00376148

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