Summary
The behavior in interfacial polycondensation of 4,4-methylenedianiline (MDA) or 4,4-oxydianiline (ODA) in water with dimethoxycarbonylterephthaloyl chloride (DCMTC) in dichloromethane with benzyltriethylammonium chloride (BTEAC) as the catalyst was examined with a Raman imaging microscope, and scanning electron microscope.
The surfaces of the polymers adjacent to the water phase had higher average molecular weight than the surfaces of the polymers adjacent to the organic phase. Moreover, the morphology of the films also changed from dense to porous along the thickness direction of the films. To obtain an interfacial film more homogeneous in morphology and molecular weight, the reaction time of interfacial condensation should not exceed 5 minutes in this system. The interfacial films were anisotropic. The chain axis of the poly(amic-ester)s mainly oriented perpendicularly to the interface in the direction of membrane growth.
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References
Koros WJ, Fleming GK (1993) J. Membrane Sci., 83: 1.
Makino H, Kusuki Y, Harada T, Shimazaki H, Isida T (1985) US Patent 4,528,004.
Makino H, Kusuki Y, Harada T, Shimazaki H, Isida T (1984) US Patent 4,440,643.
Bikson B, Nelson J (1989) US Patent 4,826,599.
Cadotte JE (1981) US Patent 4,277,344.
Chai GY, Krantz WB (1994) J. Membrane Sci., 93: 175.
Cadotte JE, Petersen RJ, Larson RE, Erickson EE (1980) Desalination, 32: 23.
Larson RE, Cadotte JE, Petersen RJ (1981) Desalination, 38: 473.
Bartels CR, Kreuz KL (1987) J.Membrane Sci., 32: 291.
Cadotte JE, King RS, Majerle RJ, Petersen RJ (1981) J. Macromol. Sci. Chem., A 15(5): 727.
Ueda U, Oishi Y, Sakai N, Imai Y (1982) Macromolecules, 15: 248.
Tagle LH, Diaz FR, Maza MPDL, Vega JC (1986) J.Polym.Sci.Polym. Chem.Ed., 24: 495.
Tagle LH, Diaz FR, Riveros PE (1986) Polymer J., 18: 501.
Morgan PW (1965) Condensation Polymers by Interfacial and Solution Methods, Interscience, New York.
Cadotte JE (1985) ACS Symp. Ser, 269, Chap. 12.
Sugawara S, Konno M, Saito S (1989) J.Membrane Sci., 44: 151.
Sundet SA, Arthur SD, Campos D, Eckman TJ, Brown RG (1987) Desalination, 64: 259.
Desai NV, Rangarajan R, Rao AV, Gary DK, Ankleshwaria BV, Mehta MH (1992) J.Membrane Sci., 71: 201.
Hurndall MJ, Jacobs EP, Sanderson RD (1992) Desalination, 86: 135.
Enkelmann V, Wegner G (1976) Makromol.Chem., 177: 3177.
Mikos AG, Kiparissides C (1991) J.Membrane Sci., 59: 205.
Chern YT, Wu BS, J. Appl. Polym. Sci., accepted.
Chem YT (1995) Makromol.Chem.Phys., 196: 3217.
Billmeyer FW, Jr. (1984) Textbook of Polymer Science, 3th ed., John Wiley and Sons, New York, NY, p. 295.
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Chern, YT., Wu, BS. & Huang, CM. The behavior of interfacial polycondensation on synthesizing of poly(amic-ester)s: homogeneity of the interfacial films. Polymer Bulletin 36, 609–616 (1996). https://doi.org/10.1007/BF00342453
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DOI: https://doi.org/10.1007/BF00342453