Summary
Total reflection X-ray fluorescence (TXRF) is used for non-destructive determination of depth profiling. A numerical processing is presented as impurity quantification in the continuum excitation TXRF without using standards. Dependences of concentration of impurities on depths ranging from a few tens to thousands Angströms are given for Fe and Cu on Si-wafer. The detection limits are in the range of 1010 atoms/cm2. The method was checked with Secondary Ion Mass Spectrometry (SIMS) and the agreement is reasonably good.
Similar content being viewed by others
References
Penka V, Hub W (1989) Fresenius Z Anal Chem 333:586
Parratt LG (1954) Phys Rev 95:359
Fan Q-M, Liu Y-W, Li D-L, Wei C-L (1990) Spectrosc Spectral Anal 10:64
Tertian R, Broll N (1984) X-Ray Spectrom 13:134
Shiraiwa T, Fujino N (1966) Jpn J Appl Phys 5:886
Fan Q-M (1991) Nucl Instrum Methods B58:287
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Fan, Q.M., Liu, Y.W., Li, D.L. et al. Determination of depth profiling of metal trace impurities on Si surface using total reflection X-ray fluorescence. Fresenius J Anal Chem 345, 518–520 (1993). https://doi.org/10.1007/BF00326342
Received:
Revised:
Issue Date:
DOI: https://doi.org/10.1007/BF00326342