Summary
An overview of the activities of the Polish Institute of Nuclear Chemistry and Technology in the field of preparation and certification of reference materials for multielement trace analysis is presented. A general strategy has been worked out and is briefly described with more detailed emphasis on the problem of data evaluation. Two geological-environmental materials recently issued [i.e. an Apatite Concentrate (CTA-AC-1) and Fine Fly Ash (CTA-FFA-1)] which were certified for 25 and 40 elements, respectively, are described. The preparation and testing of a new CRM of biological origin Oriental Tobacco Leaves (CTA-OTL-1) is presented in detail, including study of the optimum methods for drying, checking homogeneity, radiation sterilization etc. Interlaboratory comparison, in which 61 laboratories participated, yielded results enabling recommended (certified) values for 29 elements and “information values” for further 11 elements to be established.
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References
Taylor J-K (1985) Standard reference materials. Handbook for SRM Users. National Bureau of Standards, Washington
Uriano G-A, Gravatt C-C (1977) Crit Rev Anal Chem 6:361–411
Rasberry S-D (1989) In: Certified reference materials. Proceedings of ISCRM'89, May 15–18, 1989, Beijing, China, International Academic Publishers, Beijing, p 50–55
von Lehmden D-J, Jungers R-H, Lee R-E, Jr (1974) Anal Chem 436:239–245
Morrison G-H (1971) Anal Chem 43:22A-31A
Dybczyński R, Tugsavul A, Suschny O (1979) Geostandards Newsletter 3:61–87
Parr R-M (1980) IAEA/RL/69, International Atomic Energy Agency, Vienna, October
Dybczyński R (1980) J Radional Chem 60:45–54
Dybczyński R (1984) In: Quality assurance in biomedical neutron activation analysis. IAEA-TECDOC-323, International Atomic Energy Agency, Vienna, p 39–51
Parr R-M (1984) In: Quality assurance in biomedical neutron activation analysis. IAEA-TECDOC-323, International Atomic Energy Agency, Vienna, p 53–69
Dybczyński R, Polkowska-Motrenko H, Szopa Z, Samczyński Z (1989) In: Certified reference materials. Proceedings of ISCRM'89, May 15–18, 1989, Beijing, China, International Academic Publishers-Pergamon Press, Beijing, p 312–321
Dybczyński R, Polkowska-Motrenko H, Samczyński Z, Szopa Z (1991) Geostandards Newsletter 15:163–185
Mart L (1979) Fresenius Z Anal Chem 296:350–357
Sarkadi K, Vincze I (1974) Mathematical methods of statistical quality control. Akademiai Kiado, Budapest
Dybczyński R, Tugsavul A, Suschny O (1978) Analyst 103:733–744
Dybczyński R (1980) Anal Chim Acta 117:53–70
Colombo A (1986) Geostandards Newsletter 10:183–189
Abbey S, Rousseau R-M (1985) Geostandards Newsletter 9:1–16
Kocman V, Foley L-M (1987) Geostandards Newsletter 11:87–102
Dixon W-J (1953) Biometrics 9:74–89
Grubbs F-E (1950) Annals of Mathematical Statistics 21:27–58
Ferguson T-S (1961) On the rejection of outliers. In: Neyman J (ed) Fourth Berkeley Symposium on Mathematical Statistics and Probability. California Press, Berkeley, p 253–287
Grubbs F-E (1969) Technometrics 11:1–21
Dybczyński R, Veglia A, Suschny O (1980) IAEA/RL/71, International Atomic Energy Agency, Vienna, October
Ihnat M (1988) Fresenius Z Anal Chem 332:568–572
Cortes-Toro E, Parr R-M, Clements S-A (1990) IAEA/RL/128(Rev.1), International Atomic Energy Agency, Vienna
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Dybczyński, R., Polkowska-Motrenko, H., Samczyński, Z. et al. New Polish certified reference materials for multielement inorganic trace analysis. Fresenius J Anal Chem 345, 99–103 (1993). https://doi.org/10.1007/BF00322563
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DOI: https://doi.org/10.1007/BF00322563