Skip to main content
SpringerLink
Log in

Photoemission studies of BaPb1−xBixO3 and Ba1−yKyBiO3 crystals

  • Part II
  • High-Tc Superconductors
  • Published:
Fresenius' Journal of Analytical Chemistry Aims and scope Submit manuscript

Summary

Potassium and lead substituted single and polycrystalline material was examined by X-ray diffraction, X-ray topography, nonresonant microwave absorption, UPS and XPS. A covalent model instead of an ionic one is proposed. We find no evidence for a mixed valency of Bi. The valency of the Bi atoms at the unequivalent sites is close to +3. No density of states at the Fermi level has been detected.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Cox DE, Sleight AW (1976) Solid State Commun 19:969–973

    Google Scholar 

  2. Cox DE, Sleight AW (1979) Acta Crystallogr B 35:1–10

    Google Scholar 

  3. Thanh TD, Koma A, Tanaka S (1980) Appl Phys 22:205–212

    Google Scholar 

  4. Skorikov VM, Shevchuk AV, Nelyapina AJ (1988) Russ J Inorg Chem 33:1413–1415

    Google Scholar 

  5. Sugai S (1989) Solid State Commun 72:1187–1191

    Google Scholar 

  6. Sofo JO, Aligia AA, Nunez Requeiro MD (1989) Phys Rev B 40:6955–6962

    Google Scholar 

  7. Hegde MS, Barboux P, Chang CC, Tarascon JM, Venkatesan T, Wu XD, Inam A (1989) Phys Rev B 39:4752–4755

    Google Scholar 

  8. Shen Z-X, Lindberg PAP, Wells BO, Dessau DS, Borg A, Lindau I, Spicer WE, Ellis WP, Kwei GH, Ott KC, Kang J-S, Allen JW (1989) Phys Rev B 40:6912–6918

    Google Scholar 

  9. Shirai M, Suzuki N, Motizuki K (1990) J Phys Condens Matter 2:3353–3566

    Google Scholar 

  10. Hamanada N, Massidda S, Freeman AJ, Redinger J, (1989) Phys Rev B 40:4442–4452

    Google Scholar 

  11. Sakamoto H, Namatame H, Mori T, Kitazawa K, Tanaka S, Suga S (1989) J Phys Soc Jpn 56:365–369

    Google Scholar 

  12. Chaillout C, Remeika JP (1985) Solid State Commun 56:833–835

    Google Scholar 

  13. Lin CL, Qui SL, Chen J, Strongin M, Cao G, Jee C-S, Crow JE (1989) Phys Rev B 39:9607–9610

    Google Scholar 

  14. Ruckman MW, Di Marzio D, Jeon Y, Liang G, Chen J, Croft M, Hegde MS (1989) Phys Rev B 39:7359–7362

    Google Scholar 

  15. Wertheim GK, Remeika JP, Buchanan DNE (1982) Phys Rev B 26:2120–2123

    Google Scholar 

  16. Jeon Y, Liang G, Chen J, Croft M, Ruckman MW, Di Marzio D, Hegde MS (1990) Phys Rev B 41:4066–4071

    Google Scholar 

  17. Takegahara K, Kasuya T (1987) J Phys Soc Jpn 56:1478

    Google Scholar 

  18. Wagener TJ, Meyer III HM, Hill DM, Hu Y, Jost MB, Weaver JH (1989) Phys Rev B 40:4532–4537

    Google Scholar 

  19. Katsui A, Hidaka Y (1984) J Crystal Growth 66:228–230

    Google Scholar 

  20. Sleight AW, Gillson JL, Biersdedt PE (1975) Solid State Commun 17:27–28

    Google Scholar 

  21. White AE, Short K, Pech WF, Kometani T (1988) Nature 332:815–816

    Google Scholar 

  22. Doniach S, Šunjić M (1970) J Phys C Solid State Phys 3:285–291

    Google Scholar 

  23. Tougaard S (1990) J Electron Spectrosc Rel Phenom 52:243–271

    Google Scholar 

  24. Carlson TA (1975) Photoelectron and Auger spectroscopy, Table 2.2. Plenum Press, New York London

    Google Scholar 

  25. Halbritter J, Walk P, Mathes H-J, Haeuser B, Rogalla H (1988) Z Phys B — Condensed Matter 73:277–291

    Google Scholar 

  26. Contour JP, Mouvier G (1975) J Electron Spectrosc Rel Phenom 7:85–90

    Google Scholar 

  27. Nefedov VI, Salyn YaV, Leonhardt G, Scheibe R (1977) J Electron Spectrosc Rel Phenom 10:121–124

    Google Scholar 

  28. Mullins WM, Averbach BL (1988) Surf Sci 206:29–40

    Google Scholar 

  29. Peierls RE (1955) Quantum theory of solids, Oxford University Press. Oxford, p 108

    Google Scholar 

  30. Tajima S, Uchida S, Masaki A, Takagi H, Kitazawa K, Tanaka S, Sugai S (1987) Phys Rev B 35:696–703

    Google Scholar 

  31. Mattheiss LF, Hamann DR (1983) Phys Rev B 28:4227–4241

    Google Scholar 

Download references

Author information

Author notes

  1. A. Winiarski

    Present address: Institute of Physics, Silesian University, Uniwersytecka 4, PL-40-007, Katowice, Poland

Authors and Affiliations

  1. Fachbereich Physik, University of Osnabrück, P.O. Box 4469, W-4500, Osnabrück, Federal Republic of Germany

    A. Winiarski, G. Wübbeler, Chr. Scharfschwerdt, E. Clausing & M. Neumann

Authors
  1. A. Winiarski
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. G. Wübbeler
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Chr. Scharfschwerdt
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. E. Clausing
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. M. Neumann
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Winiarski, A., Wübbeler, G., Scharfschwerdt, C. et al. Photoemission studies of BaPb1−xBixO3 and Ba1−yKyBiO3 crystals. Fresenius J Anal Chem 341, 296–300 (1991). https://doi.org/10.1007/BF00321567

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00321567

Keywords

Search

Navigation