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Controlled radical polymerization

Synthesis of chloromethyl styrene/styrene block copolymers

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Summary

The free radical polymerization of chloromethylstyrene (CMS) with benzoyl peroxide (BPO) as initiator and 2,2,6,6 tetramethyl-1-piperidiniloxy (Tempo) as counter radical was studied. The living character was demonstrated by the linear dependence of \(\overline {M_n } \) versus conversion like that the control with polydispersity lower than 1,5. In a second step, styrene was introduced in polychloromethylstyrene capped with Tempo to produce PCMS-b-PS block copolymers (12,000/60,000) with and PCMS-Tempo macroinitiator efficiency closed to 85%.

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Authors and Affiliations

  1. Laboratoire de Chimie Appliquée, UPRES A 50760, Ecole Nationale Supérieure de Chimie de Montpellier, 8, Rue de l'Ecole Normale, F-34053, Montpellier Cedex 1, France

    Denis Bertin & Bernard Boutevin

Authors
  1. Denis Bertin
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  2. Bernard Boutevin
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Bertin, D., Boutevin, B. Controlled radical polymerization. Polymer Bulletin 37, 337–344 (1996). https://doi.org/10.1007/BF00318066

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  • DOI: https://doi.org/10.1007/BF00318066

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