Abstract
The uptake of water in quartz at 1.5 GPa total pressure, 1173 K and high water fugacity, over times up to 24 h, has been investigated using a newly developed assembly to prevent microcracking. It is found that the uptake is small, and below the detectability of the presently used technique of infrared spectroscopy and serial sectioning. This observation reflects either a low value for the diffusivity or the solubility or a combination of both, and is in agreement with the observations of Kronenberg et al. (1986) and Rovetta et al. (1986). It brings into question the interpretation of the early experiments on water weakening by Griggs and Blacic (1964) and the recent estimates of the solubility and diffusivity by Mackwell and Paterson (1985).
Rults of a combined T.E.M., light-scattering and infrared-spectroscopy investigation of ‘wet’ synthetic quartz before and after heating at 0.1, 300 and 1500 MPa total pressure and 1173 K, strongly suggest that the water in ‘wet’ quartz is mainly in the form of H2O in inclusions, consistent with the solubility being low, possibly less than 100 H/106Si.
From these observations, water-containing inclusions appear to play a major role in the plasticity of quartz, while any role of water in solid solution remains to be clarified.
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References
Aines RD, Kirby SH, Rossman GR (1984) Hydrogen speciation in synthetic quartz. Phys Chem Minerals 11:204–212
Ashby MF, Brown LM (1963a) Diffraction contrast from spherically symetrical coherency strains. Philos Mag 8:1063–1103
Ashby MF, Brown LM (1963b) On the diffraction contrast from inclusions. Philos Mag 8:1649–1676
Atkinson BK (1984) Subcritical crack growth in geological materials. J Geophys Res 89:4077–4114
Baëta RD, Ashbee KHG (1970a) Mechanical deformation of quartz. I Constant strain-rate compression experiments. Philos Mag 22:601–623
Baëta RD, Ashbee KHG (1970b) Mechanical deformation of quartz. II Stress relaxation and thermal activation parameters. Philos Mag 22:625–635
Bambauer HU, Brunner GD, Laves F (1969) Light scattering of heat-treated quartz in relation to hydrogen containing defects. Am Mineral 54:718–724
Blacic JD (1975) Plastic deformation mechanisms in quartz: the effect of water. Tectonophysics 27:271–294
Blacic JD (1981) Water diffusion in quartz at high pressure: tectonic implications. Geophys Res Lett 8:721–723
Blacic JD, Christie JM (1984) Plasticity and hydrolytic weakening of quartz single crystals. J Geophys Res 89:4223–4239
Brunner GO von, Wondratschek H, Laves F (1961) Ultrarot Untersuchungen über den Einbau von H in natürlichen Quartz. Z Electrochem 65:735–750
Dodd DM, Fraser DB (1966) Optical determination of OH in fused silica. J Appl Phys 37:3911
Doukhan J-C, Trepied C (1979) Plasticity of quartz: crystallographic models and T.E.M. observations. Bull Minéral 108:97–123
Doukhan J-C, Trepied C (1985) Plastic deformation of quartz single crystals. Bull Minéral 108:97–123
Elphick SC, Dennis PF, Graham CM (1986) An experimental study of the diffusion of oxygen in quartz and albite using an over growth technique. Contrib Mineral Petrol 92:322–330
Etheridge MA, Wall VJ, Cox SF, Vernon RH (1984) High fluid pressures during metamorphism and regional deformation, implications for mass transport and deformation mechanisms. J Geophys Res 89:4344–4358
Gerretsen J, Paterson MS, Bitmead J (1985) Improved procedures for diffusing water into quartz at high temperature and pressure. EOS, Trans Am Geophys Union 65:1107
Gerretsen J, McLaren AC, Paterson MS (1987) Evolution of water inclusions in wet synthetic quartz as a function of temperature and pressure. EOS, Trans Am Geophys Union 68:1453
Griggs DT (1967) Hydrolytic weakening of quartz and other silicates. Geophys J Roy Astron Soc 14:19–31
Griggs DT (1974) A model of hydrolytic weakening in quartz. J Geophys Res 79:1655–1661
Griggs DT, Blacic JD (1964) The strength of quartz in the ductile region. Trans Am Geophys U 48:102–103
Griggs DT, Blacic JD (1965) Quartz: anomalous weakening of synthetic crystals. Science 147:292–295
Grutzeck MW (1985) An artifact of sample preparation dissolution-precipitation on quartz surfaces. J Mater Sci Lett 4:277–280
Hagon JP, Stoneham AM, Jaros M (1987) Transport processes in silicon oxidation II. Wet oxidation. Philos Mag B 55:225–235
Halbach H, Chatterjee ND (1982) An experimental Redlich-Kwong type equation of state for water to 1000° C and 200 kbar. Contrib Mineral Petrol 79:337–345
Heggie M, Jones R (1986) Models of hydrolytic weakening in quartz. Philos Mag A 53:L65-L70
Hirsch PB (1981) Plastic deformation and electronic mechanisms in semi conductors and insulators. J Phys (Paris) Colloq C3, 42:C3–149 to C3–159
Hobbs BE (1984) Point defect chemistry of minerals under a hydrothermal environment. J Geophys Res 89:4026–4038
Hobbs BE (1981) The influence of metamorphic environment upon the deformation of minerals. Tectonophysics 78:335–383
Hobbs BE, McLaren AC, Paterson MS (1972) Plasticity of single crystals of synthetic quartz. In: Heard HC et al. (eds), Flow and Fracture of Rocks. Am Geophys Union, Geophysical Monogr 16:29–53
Hobbs BE, Tullis TE (1979) The influence of pressure on hydrolytic weakening in quartz (abstract). EOS, Trans Am Geophys Union 60:370
Ishido T, Nishizawa O (1984) Effects of ζ-potential on the microcrack growth in rock under relative low uniaxial compression. J Geophys Res 89:4153–4160
Jones ME (1975) Water weakening of quartz and its application to natural rock deformation. J Geol Soc Lond 131:429–432
Jones ME (1978) The influence of hydrostatic pressure on the precipitation of structure-bound water in micro-inclusions in quartz. Philos Mag A 37:703–706
Kats A (1962) Hydrogen in alpha quartz. Philips Research Reports 17:133–195, 201–279
Kennedy GC, Holster WT (1966) Pressure-volume-temperature and phase relations of water and carbon. In: Clark Jr, SP (ed) Handbook of physical constants. Geol Soc Am Mem 97:371–383
Kekulawala KRSS (1978) Hydrolytic weakening of quartz. Unpublished Ph.D. Thesis, R.S.E.S., Australian National University
Kekulawala KRSS, Paterson MS, Boland JN (1981) An experimental study of the role of water in quartz deformation. In: Carter NL et al. (eds) Mechanical behavior of crustal rocks. Am Geophys Union, Geophys Monogr 24:49–60
Kirby SH, Kronenberg AK (1984) Hydrolytic weakening of quartz: Uptake of molecular water and the role of microfracturing (abstract). EOS, Trans Am Geophys Union 65:16
Kronenberg AK, Kirby SH, Aines RD, Rossman GR (1983) Hydrogen uptake in hydrothermally annealed quartz: implications of hydrolytic weakening (abstract). EOS Trans Am Geophys Union 64:839
Kronenberg AK, Kirby SH, Aines RD, Rossman GR (1986) Solubility and diffusional uptake of hydrogen in quartz at high water pressures: implications for hydrolytic weakening. J Geophys Res 91:12723–12744
Mackwell SJ, Paterson MS (1985) Water related diffusion and deformation effects in quartz at pressures of 1500 and 300 MPa. In: Schock RN (ed) Point defects in minerals. Am Geophys Union, Geophys Monogr 31:141–150
McLaren AC, Cook RF, Hyde ST, Tobin RC (1983) The mechanisms of the formation and growth of water bubbles and associated dislocation loops in synthetic quartz. Phys Chem Minerals 9:79–94
McLaren AC, Phakey DP (1965) Dislocations in quartz observed by transmission electron microscopy. J Appl Phys 36:3244–3246
McLaren AC, Phakey DP (1966) Electron microscope study of brazil twin boundaries in amethyst quartz. Phys Status Solidi 13:413–422
McLaren AC, Retchford JA (1969) T.E.M. study of the dislocations in plastically deformed synthetic quartz. Phys Status Solidi 33:657–688
McLaren AC, Retchford JA, Griggs DT, Christie JM (1967) Transmission electron microscopy study of Brazil twins and dislocations experimentally produced in natural quartz. Phys Status Solidi 19:631–644
Mirwald RW, Mossonne HJ (1980) The low-high quartz and quartz-coesite transition to 40 kbar between 600° and 1000° C and some reconnaissance data on the effect of NaAlO2 component on the low quartz-coesite transition. J Geophys Res 85:6983–6990
Morrison-Smith DJ (1974) Deformation of synthetic quartz. Unpublished PhD Thesis, Australian National University
Morrison-Smith DJ, Paterson MS, Hobbs BE (1976) An electron microscope study of plastic deformation in single crystals of synthetic quartz. Tectonophysics 33:43–79
Nakamura Y (1974) The system SiO2-H2O-H2 at 5 kbar. Carnegie Institution of Washington, Year Book, 73:259–263
Neuber H (1958) Kerbspannungslehre. 2nd edition. Springer Verlag, Berlin Heidelberg New York
Ord A, Hobbs BE (1983) Oxygen dependence of the hydrolytic weakening effect in quartz. EOS Trans Am Geophys U 64:839
Ord A, Hobbs BE (1986) Experimental control of the water-weakening effect in quartz. In: Hobbs BE, Heard HC (eds) Mineral and Rock Deformation: Laboratory Studies. Am Geophys Union, Geophys Monogr 3:51–72
Paterson MS (1982) The determination of hydroxyl by infrared absorption in quartz, silicate glasses and similar materials. Bull Minéral 105:20–26
Paterson MS (1985) Dislocations and geological deformation, In: Dislocations and Properties of Real Materials. The Institute of metals: 359–377
Paterson MS (1986) The thermodynamics of water in quartz. Phys Chem Minerals 13:245–255
Paterson MS (1988) The interaction of water with quartz and its influence in dislocation flow — an overview. Submitted to Karato S, Toriumi M (eds) Rheology of Solids and of the Earth, Oxford Univ. Press, Oxford
Paterson MS, Kekulawala KRSS (1979) The role of water in quartz deformation. Bull Minéral 102:92–98
Poirier JP (1986) Creep of crystals. Cambridge Univ. Press, Cambridge
Rovetta MR, Blacic JD, Holloway JR (1986) Solubility of hydroxyl in natural quartz annealed in water at 900° C an 1.5 GPa. Geophys Res Lett 13:145–148
Sawyer B (1972) Q capability indications from infrared absorption measurements for Na2CO3 process cultured quartz. IEEE Trans. Sonics and Ultrasonics, SU19:41–44
Tullis J, Shelton GL, Yund RA (1979) Pressure dependence of rock strength, implications for hydrolytic weakening. Bull Minéral 102:110–114
Tullis J, Yund RA (1985) Hydrolytic weakening of quartz aggregates: requirement for rapid penetration. EOS Trans Am Geophys U 66:1084
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Gerretsen, J., Paterson, M.S. & McLaren, A.C. The uptake and solubility of water in quartz at elevated pressure and temperature. Phys Chem Minerals 16, 334–342 (1989). https://doi.org/10.1007/BF00199553
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DOI: https://doi.org/10.1007/BF00199553