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NMHC in the marine atmosphere: Preliminary results of monitoring at Amsterdam Island

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Abstract

Between January 1984 and May 1987, C2 to C5 NMHC concentrations, and Radon-222 activities were measured at Amsterdam Island in the Indian Ocean. A large variability of about one order of magnitude was observed in the NMHC concentrations. Most of the samples were collected under marine influence. Using ethene as a reference compound for marine emissions, it appears that the NMHC/ethene composition of the air and its variability directly reflect the composition of dissolved gases in surface seawater. Only the ethane/ethene ratio presents a significant deviation from this typical composition and this can be attributed to a continental component. At sea level, the reation frequency of OH radicals with the NMHC is similar to that of methane and carbon monoxide. Thus, the contribution of marine NMHC should be taken into account in the modelling of oxidants in remote atmospheres.

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References

  • Atkinson, R., 1986, Kinetics and mechanisms of the gas-phase reactions of the hydroxyl radical with organic compounds under atmospheric conditions, Chem. Rev. 8, 69–201.

    Google Scholar 

  • Bonsang, B. and Lambert, G., 1985 Nonmethane hydrocarbons in an oceanic atmosphere. J. Atmos. Chem. 2, 257–271.

    Google Scholar 

  • Bonsang, B., Kanakidou, M. and Lambert, G., 1987, Non methane hydrocarbons chemistry in the atmosphere of an equatorial forest: A case of indirect photochemical production of OH radicals, Geophys. Res. Lett. 14, 1250–1253.

    Google Scholar 

  • Bonsang, B., Kanakidou, M., Lambert, G., and Monfray, P., 1988a, The marine source of C2-C6 aliphatic hydrocarbons. J. Atmos. Chem. 6, 3–20.

    Google Scholar 

  • Bonsang, B., Kanakidou, M., Lambert, G., Le Roulley, J. C., Martin, D., and Sennequier, G., 1988b, Sources and sinks of NMHC deduced from their vertical distributions Application to OH radicals concentrations, International Congress of Geochemistry and Cosmochemistry, 29 Aug.–2 Sept. 1988, Paris.

  • Bonsang, B., Kanakidou, M., and Lambert, G., 1989, Sur la faible variabilité de composition relative des hydrocarbures légers non méthaniques dissous dans l'eau de mer superficielle, C.R. Acad Sci. II 308, 495–500.

    Google Scholar 

  • Ehhalt, D. H., Rudolph, J., Meixer, F., and Schmidt, U., 1985. Measurements of selected C2-C5 hydrocarbons in the background troposphere: vertical and latitudinal variations. J. Atmos. Chem. 3, 29–52.

    Google Scholar 

  • Greenberg, J. P., and Zimmerman, P. R., 1984, Nonmethane hydrocarbons in remote tropical, coritinental, and marine atmospheres, J. Geophys. Res. 89, 4767–4778.

    Google Scholar 

  • Hov, O., Penkett, S. A., Isaksen, I. S. A., and Semb, A., 1984, Organic gases in the Norwegian arctic, Geophys. Res. Lett. 11, 425–428.

    Google Scholar 

  • Kanakidou, M., Bonsang, B., Le Roulley, J. C., Lambert, G., Martin, D., and Sennequier, G., 1988, Marine source of atmospheric acetylene, Nature 333, 51–52.

    Google Scholar 

  • Kanakidou, M., Bonsang, B., and Lambert, G., 1989, Light hydrocarbons vertical profiles and fluxes in a french rural area, Atmos. Environ. 23, 921–927.

    Google Scholar 

  • Rasmussen, R. A., and Khalil, M. A. K., 1982, Latitudinal distributions of trace gases in and above the boundary layer, Chemosphere 11, 227–235.

    Google Scholar 

  • Rudolph, J. and Ehhalt, D. H., 1981, Measurements of C2-C5 hydrocarbons over the North Atlantic, J. Geophys. Res. 86, 11959–11964.

    Google Scholar 

  • Rudolph, J., 1986, Comparison of biogenic and man-made light hydrocarbons-Large scale distribution and impact on the chemistry of the atmosphere, 2nd International Symposium on Biosphere-Atmosphere Exchanges, 16–21 March 1986, Mainz (Germany).

  • Rudolph, J., Khedim, A., and Wagenbach, D., 1989, The seasonal variation of light non-methane hydrocarbons in the antarctic troposphere, J. Geophys. Res. 94, 13039–13044.

    Google Scholar 

  • Polian, G., 1984, Atmospheric transports in the Southern Hemisphere, and global balance of Rn-222 (in French), PhD thesis, Univ. Pierre et Marie Curie, Paris, France.

  • Polian, G., Lambert, G., Ardouin, B., and Jegou, A., 1986, Long-range transport of continental radon in subantarctic and antarctic areas, Tellus 38B, 178–189.

    Google Scholar 

  • Singh, H. B. and Salas, L. J., 1982, Measurement of selected light hydrocarbons over the Pacific Ocean: latitudinal and seasonal variations. Geophys. Res. Lett. 8, 842–845.

    Google Scholar 

  • Singh, H. B., Viezee, W., and Salas, L. J., 1988, Measurements of selected C2-C5 hydrocarbons in the troposphere: Latitudinal, vertical, and temporal variations, J. Geophys. Res. 93, 15861–15878.

    Google Scholar 

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Bonsang, B., Kanakidou, M. & Lambert, G. NMHC in the marine atmosphere: Preliminary results of monitoring at Amsterdam Island. J Atmos Chem 11, 169–178 (1990). https://doi.org/10.1007/BF00053673

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