Abstract
Our purpose in this research work is to be synthesized Se75Te22In3 and Se75Te19In6 chalcogenide alloys which have been synthesized by using melt quenching method. Physical vapor condensation technique (PVCT) was used to prepared nano-thin films of synthesized Se75Te22In3 and Se75Te19In6 alloys. From HRXRD measurement clear that prepared thin films have amorphous texture. The morphological studies using FESEM suggest that the nanochalcogenide thin films contain particles of size ranges from 30–60 nm. Based on UV–Visible spectroscopy studies, absorption coefficient (α) is found to increase with photon energy and had significant change due to the change in Indium concentration. The optical absorption obeys rule of direct transition. Optical band gap increases from 2.18 to 2.22 eV when Indium content increases. These studies suggest that our prepared materials have possible application in different optical and storage devices.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
References
Seddon AB (1995) Chalcogenide glasses: a review of their preparation, properties, and applications. J Non-Cryst Solids 184:44–50
Khan SA, Tiwari G, Tripathi RP, Alvi MA, Khan ZH, Al-Agel FA (2014) Structural, optical, and structural characterization of polycrystalline Ga15Te85-XZnX thin films. Adv Sci Lett 20:1715–1718
Khan SA, Al-Agel FA, Al-Ghamdi AA (2010) Optical characterization of nanocrystalline Se85Te10Pb5 and Se80Te10Pb10 chalcogenides. Superlattices Microstruct 47:695–704
Ni J, Bi X, Jiang Y, Li L, Lu J (2017) Bismuth chalcogenide compounds Bi2X3 (X=O, S, Se): Applications in electrochemical energy storage. Nano Energy 34:356–366
Bhatt VS, Yadav AK, Dixit D, Tomy CV (2022) High-temperature solution growth of large size chalcogenide FeTXSe (T:Fe, Co) superconducting single crystals. Superconductivity 3:100016
Andzane J, Felsharuk A, Sarakovskis A, Malinovskis U, Kauranens E, Bechelany M, Niherysh KA, Komissarov IV, Erts D (2021) Thickness-dependent properties of ultrathin bismuth and antimony chalcogenide films and their application in thermoelectric generators. Mater Today Energy 19:100587
Nur-E-Alam M, Basher MK, Vasiliev M, Das N (2021) Physical vapor-deposited silver (Ag)-based metal-dielectric nanocomposites for thin-film and coating applications. Appl Sci 6746
Yavorskyi R, Nykyruy L, Wisz G (2019) Structural and optical properties of cadmium telluride obtained by physical vapor deposition technique. Appl Nanosci 9:715–724
Alvi MA, Al-Ghamdi AA, Madani JH (2014) Synthesis and characterization of Bi doped Se–Te nanostructured thin films. Measurement 58:325–329
Benjamin LK, Dube P, Tabi CB, Muiva CM (2021) Physical, linear and nonlinear optical properties of amorphous Se90-xTe10Mx (M = Zn, In, Pb, x = 0, 5) chalcogenide thin films by electron-beam deposition. J Non-Cryst Solids 557:120646
Khan SA, Sahani RM, Tripathi RP, Shaheer Akhtar M, Srivastava A (2021) Influence of gamma-irradiation on the optical and structural properties of Se85Te15-xBix nano-thin chalcogenide films. Radiat Phys Chem 188:109659
Alqahtani A, Yakout HA, Shaaban ER, Qasem A (2022) Extended study into the prominence of Al content in controlling optical parameters, thermal properties and dielectric behavior of amorphous Al-Se-Te thin films for optoelectronic applications. Opt Laser Technol 156:108459
Mannu P, Palanisamy M, Bangaru G, Ramakrishnan S, Ramcharan M, Kandasami A (2022) Electrical transport properties of Indium chalcogenide thin films and their thermoelectric applications. Mater Today: Proc 48(2):115–118
Tripathi RP, Akhtar SM, Khan SA (2018) Thermally deposited Se85In15–x Sbx chalcogenide thin films: structural, electrical and optical properties. Mater Focus 7(2):251–258
Tripathi RP, Alvi MA, Khan SA (2020) Investigations of thermal, optical and electrical properties of Se85In15−xBix glasses and thin films. J Therm Anal Calorim 146:2261–2272
Srivastava A, Tiwari SN, Lal JK, Khan SA (2019) Phase transformation in Se75Te13In12 chalcogenide thin films. Glass Phys Chem 45:111–118
Tripathi RP, Zulfequar M, Khan SA (2016) Structural, optical and electrical properties of Se85In9Bi6 nanochalcogenide thin film. Curr Nanomater 1(3):176–182
Lal JK, Khan SA, Al-Gahamdi AA, Khan ZH (2009) Characterization of amorphous Se97Te3 nanoparticles prepared by ball milling. Int J Nanomanuf 4:208–218
Khan SA, Al-Agel FA, Faidah AS, Yaghmour SJ, Al-Gahamdi AA (2010) Characterization of Se88Te12 nanostructured chalcogenide prepared by ball milling. Mater Lett 64:1391–1393
Urbach F (1953) The long-wavelength edge of photographic sensitivity and of electronic absorption of solids. Phys Rev 92:1324
Dow JD, David R (1972) Toward a unified theory of urbach’s rule and exponential absorption edges. Phys Rev B 5:594
Acknowledgements
We are thankful to Prof. Zishan H. Khan Dept. of Applied Science and Humanities, F/O Engineering and Technology, Jamia Millia Islamia, New Delhi for providing research facilities in his research lab.
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Ethics declarations
Conflict of Interest
There are no as such conflicts for the declaration in this manuscript.
Rights and permissions
Copyright information
© 2024 The Author(s), under exclusive license to Springer Nature Singapore Pte Ltd.
About this paper
Cite this paper
Khan, I.H., Tripathi, R.P., Khan, S.A. (2024). Studies on Nanochalcogenide Se75Te22In3 and Se75Te19In6 Thin Films Synthesized by Physical Vapor Condensation Technique. In: Khan, Z.H., Jackson, M., Salah, N.A. (eds) Recent Advances in Nanomaterials. ICNOC 2022. Springer Proceedings in Materials, vol 27. Springer, Singapore. https://doi.org/10.1007/978-981-99-4878-9_52
Download citation
DOI: https://doi.org/10.1007/978-981-99-4878-9_52
Published:
Publisher Name: Springer, Singapore
Print ISBN: 978-981-99-4877-2
Online ISBN: 978-981-99-4878-9
eBook Packages: Chemistry and Materials ScienceChemistry and Material Science (R0)