Abstract
This paper systematically introduces the latest research progress of graphene-based energetic compounds in recent years from three aspects: the preparation method of graphene-based energetic compounds, the desensitization effect and the catalytic effect of graphene-based materials on energetic materials. The preparation methods of graphene-based energetic compounds can be divided into physical combination and chemical bonding. The insensitive agent composed of graphene-based materials can reduce the mechanical sensitivity of energetic materials. Catalysts composed of graphene-based materials can significantly improve the combustion performance of energetic materials. Graphene-based composite energetic materials possess excellent combustion thermochemical properties. Finally, the key research directions and research prospects of graphene-based energetic compounds in the future are proposed.
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References
K.S. Novoselov, A.K. Geim, S.V. Morozov, D. Jiang, Y. Zhang, S.V. Dubonos, I.V. Grigorieva, A.A. Firsov, Electric field effect in atomically thin carbon films. Science 306, 666–669 (2004)
B.Y. Nong, C.W. Lai , Z.B. Liu, B.M. Liang, X.H. Zhang, Study on microstructure and mechanical properties of graphene reinforced aluminum matrix composite. Hot Work. Technol. 46, 144–146+150 (2017)
A.A. Balandin, S. Ghosh, W. Bao, I. Calizo, D. Teweldebrhan, F. Miao, C.N. Lau, Superior thermal conductivity of single-layer graphene. Nano Lett. 8, 902–907 (2008)
M.D. Stoller, S. Park, Y. Zhu, J. An, R.S. Ruoff, Graphene-based ultracapacitors. Nano Lett. 8, 3498–3502 (2008)
C. Lee, X. Wei, J.W. Kysar, J. Hone, Measurement of the elastic properties and intrinsic strength of monolayer graphene. Science 321, 385–388 (2008)
B.Y. Ye, J.Y. Wang, C.W. An, B.S. Yu, W. Ji, H.Q. Li, Preparation and properties of CL-20 based composite energetic material. J. Solid Rocket Technol. 40, 199–203 (2017)
Y.F. Lan, X.Y. Li, Y.J. Luo, Research progress on application of graphene in energetic materials. Chin. J. Explos. Propellants 46 144–146+150 (2017)
C. Niu, B. Jin, R. Peng, Y. Shang, Q. Liu, Preparation and characterization of insensitive HMX/rGO/G composites via in situ reduction of graphene oxide. RSC Adv. 7, 32275–32281
L. Yu, Investigation on Graphene Functionalized with Energetic Groups Doctor (Beijing Institute of Technology, 2015)
F.Y. Guan, L. Yu, H. Ren, Q.J. Jiao, J. Liu, Synthesis of nitrified graphene oxide and its catalytic activity for ammonium perchlorate decomposition. ACTA ARMAMENTARII 41, 1323–1329
T. Zhang, Y. Guo, Y.Y. Li, Z.Q. Guo, H.X. Ma, Effect of nitrogen-doped graphene oxide on thermal decomposition of HMX. Chin. J. Explos. Propellants 42, 346–351 (2019)
X.B. Wang, J.Q. Li, Y.J. Luo, Preparation and thermal decomposition behaviour of ammonium perchlorate/graphene aerogel nanocomposites. Chin. J. Explos. Propellants 35, 76–80 (2012)
H. Wei, P.J. Liu, G.Q. He, G. Michael, Q.L. Yan, Highly reactive metastable intermixed composites (MICs): preparation and characterization. Adv. Mater. 30, e1706293 (2018)
L. Zhang, J.Y. Huang, Z.H. Xiao, Y. He, K.G. Liu, Z.C. Lx, B.X. Xiang, J.P. Qu, L.B. Kong, Progress in fabrication and growth mechanisms of mullite whiskers. J. Ceram. 41, 880–893 (2020)
K.G. Guo, X.L. Song, Y. Wang, C.L. Liu, Y. Kou, Preparation and characterization of submicron LLM-105 and LLM-105/GO composite energetic materials. Initiat. Pyrotech. 33–7 (2019)
B. Ye, C. An, Y. Zhang, C. Song, X. Geng, J. Wang, One-step ball milling preparation of nanoscale CL-20/graphene oxide for significantly reduced particle size and sensitivity. Nanoscale Res. Lett. 13, 42 (2018)
H.Y. Wang, X. Cao, J.L. Wo, Y.B. Xu, Y.P. Shang, Preparetion and thermal decomposition characteristics of TKX-50/GO composit energetic materials. Chin. J. Explos. Propellants 43, 631–635 (2020)
Y.F. Lan, Investigation on Preparation and Characterization of Graphene-Based Nanocomposites and Their Catalytic Application for Ammonium Perchlorate Doctor (Beijing Institute of Technology, 2016)
T.T. Li, J.K. Li, Y. Hu, Y.H. Ye, R.Q. Shen, Study on preparation and electric exploding performance of Al-CuO/graphene oxide energetic igniting bridge film. Initiat. Pyrotech. 15–9 (2018)
Y. Hu, B. Tao, D. Hao, R. Fan, D. Xia, K. Lin, A. Pang, Y. Yang, Fabrication and mechanistic study of AP/nAl/PTFE spherical encapsulated energetic materials with enhanced combustion performance. Chem. Eng. Sci. 222, 115701
T. Zhang, Z. Ma, G. Li, Z. Wang, B. Zhao, Y. Luo, Electrostatic interactions for directed assembly of high performance nanostructured energetic materials of Al/Fe2O3/multi-walled carbon nanotube (MWCNT). J. Solid State Chem. 237, 394–403 (2016)
R. Thiruvengadathan, S.W. Chung, S. Basuray, B. Balasubramanian, C.S. Staley, K. Gangopadhyay, S. Gangopadhyay, A versatile self-assembly approach toward high performance nanoenergetic composite using functionalized graphene. Langmuir Acs J. Surf. Colloids 30, 6556–6564 (2014)
X.B. Wang, J.Q. Li, Y.J. Luo, Effect of drying methods on the structure and thermal decomposition behavior of ammonium perchlorate/graphene composites. Acta Phys. Chim. Sin 29, 2079–2086
Y. Lan, X. Wang, Y. Luo, Preparation and characterization of GA/RDX nanostructured energetic composites. Bull. Mater. Sci. 39, 1701–1707 (2016)
Y. Lan, G. Li, X. Li, Sol-gel method to prepare graphene/Fe2O3 aerogel and its catalytic application for the thermal decomposition of ammonium perchlorate. Nanotechnol. Wkly. 395 (2015)
Y.F. Lan, Y.J. Luo, Preparation and characterization of graphene aerogel/ammonium nitrate nano composite energetic materials. Chin. J. Explos. Propellants 38, 15–18+38
R. Li, J. Wang, P.S. Jin, H. Cheng, G.C. Yang, Preparation and characterization of insensitive HMX/Graphene oxide composites. Propellants Explos. Pyrotech. 38, 798–804 (2013)
S. Yuan, Z.Q. Li, X.H. Duan, Q.P. Luo, X. Liu, C.H. Pei, Preparation and thermal decomposition properties of NGO/NC composite energetic materials. Chin. J. Energ. Mater. 25, 203–208 (2017)
J.K. Li, X.X. Ma, Y. Hu, Y.H. Ye, R.Q. Shen, Preparation and characterization of KNO3/GO composite energetic materials. Explos. Mater. 45, 1–5 (2016)
X.D. Li, B. Huan, Z.Q. Qiao, J. Chen, G.C. Yang, Combustion characteristic of rGO/CL-20 self-supporting fiber-shaped solid propellant. Chin. J. Energ. Mater. 26, 1003–1008 (2018)
L. Li, J. Gu, D.C. Huang, B.W. Tao, H.S. Wang, Y.F. He, J.J. Hu, Desensitization of aluminum hydride( AlH3) by graphene oxide. J. Solid Rocket Technol. 42, 66–71 (2019)
W. He, J.H. Guo, C.K. Cao, X.K. Liu, J.Y. Lv, S.W. Chen, P.J. Liu, Q.L. Yan, Catalytic reactivity of graphene oxide stabilized transition metal complexes of triaminoguanidine on thermolysis of RDX. J. Phys. Chem. C Nanomater. Interfaces 122, 14714–14724 (2018)
A. Dey, J. Athar, P. Varma, H. Prasant, A. Sikder, S. Chattopadhyay, Graphene-iron oxide nanocomposite (GINC): an efficient catalyst for ammonium perchlorate (AP) decomposition and burn rate enhancer for AP based composite propellant. Rsc Adv. 5, 723–724
A. Dey, V. Nangare, P.V. More, M.A. Shafeeuulla Khan, P.K. Khann, A.K. Sikder, S. Chattopadhyay, Graphene titanium dioxide nanocomposite (GTNC): one pot green synthesis and its application in solid rocket propellant. Rsc Adv. 5, 63777–63785 (2015)
X.X. Zhang, J.Y. Lu, W. He, S.W. Chen, Z.J. Yang, Q.L. Yan, Graphene-templated energetic 5, 5′-Bistetrazole coordination polymers and their catalytic effects on thermal decomposition of RDX and AP. Chin. J. Energ. Mater. 27, 749–758 (2019)
J.J. Wang, In situ Preparation and Properties of MgWO4-GO and Cu-Co/GO Composites Master (Northwest University, 2020)
X.L. Jia, C.H. Hou, J.Y. Wang, Y.X. Tan, Y.P. Zhang, C. Li, Research progress on the desensitization technology of nitramine explosives. Chin. J. Explos. Propellants 41, 326–333 (2018)
C.Y. Zhou, C.J. Tang, S.X. Wu, J. Gu, Z.Y. Li, N. Yao, Combustion and agglomeration behavior of graphene-coated aluminum powder in HTPB propellant. J. Solid Rocket Technol. 43, 38–44 (2020)
C.H. Niu, The Research of Insensitive Performance forCL-20 and HMX with Carbon Nanomaterials Master (Southwest University of Science and Technology, 2018)
B.Y. Ye, Study on the Construction and Basic Application of Graphene Materials Modified Energetic Composites Doctor (North University of China, 2018)
Z.H. Jin, Comparative Research on Properties of the HNIW Modified by Nano-carbon Materials Master (BeiJing Institute of Technology, 2016)
Z. Li, Y. Wang, Y. Zhang, L. Liu, S. Zhang, CL-20 hosted in graphene foam as a high energy material with low sensitivity. Rsc Adv. 5, 98925–98928
Y. Li, Studies on Lead Styphnate Modified by the New Nano-carbon Materials in Thermal Analysis Master (Beijing Institute of Technology, 2016)
Q. Wang, J. Liu, H. Ren, Q.J. Jiao, Effect of reduced graphene oxide on the impact sensitivity and electrostatic sensitivity of B/KNO3 ignition powder. Chin. J. Energ. Mater. 26, 875–880 (2018)
Z.H. Wang, Study on Nomenclature and Properties of B·KNO3 Ignition Doped with Carbon Nanomaterials Master (China Academy of Engineering Physics, 2019)
T.T. Li, Research on Carbon based Nano CU(N3)2 Composite Energetic Materials Master (Nanjing University of Science & Technology, 2018)
S. Isert, L. Xin, J. Xie, S.F. Son, The effect of decorated graphene addition on the burning rate of ammonium perchlorate composite propellants. Combust. Flame 183, 322–329 (2017)
P. Ye, Y.F. Lu, P.F. Xu, X. Hu, J.X. He, Q. Wang, C.P. Guo, Preraration of CoFe2O4@C nano-composites and their catalytic performance for the thermal decomposition of ammonium perchlorate. Chin. J. Explos. Propellants 42, 358–362 (2019)
J. Cheng, Y. Zheng, Z. Li, Z. Liu, L. Li, F. Zhao, S. Xu, Catalytic reaction of ammonium perchlorate with energetic cobalt complex of 2,6-diamino-3,5-dinitropyrazine-1-oxide during thermal decomposition process. J. Therm. Anal. Calorim. 129, 1875–1885 (2017)
V.V. Boldyrev, Thermal decomposition of ammonium perchlorate. Thermochim. Acta 443, 1–36 (2006)
L. Mallick, S. Kumar, A. Chowdhury, Thermal decomposition of ammonium perchlorate—A TGA–FTIR–MS study: Part I. Thermochim. Acta 610, 57–68 (2015)
N.K. Memon, A.W. McBain, S.F. Son, Graphene oxide/ammonium perchlorate composite material for use in solid propellants. J. Propuls. Power 32(2016)
J. Cheng, X.Y. Shen, R. Wang, R.X. Zhang, Z.L. Liu, Y.G. Hao, H.P. Su, Preparation and thermal decomposition behavior of energetic functionalized graphene oxide and its catalytic effect on the thermal decomposition of AP. Chin. J. Explos. Propellants 43, 180–187 (2020)
M. Zhang, F.Q. Zhao, Y.J. Yang, W.G. Qu, N. Li, J.K. Zhang, Advances in the effects of graphene based materials on properties of energetic materials. Chin. J. Energ. Mater. 26, 1074–1082 (2018)
N. Li, Z. Geng, M. Cao, L. Ren, X. Zhao, B. Liu, Y. Tian, C. Hu, Well-dispersed ultrafine Mn3O4 nanoparticles on graphene as a promising catalyst for the thermal decomposition of ammonium perchlorate. Carbon 55, 124–32 (2013)
Y. Yuan, W. Jiang, Y. Wang, P. Shen, F. Li, P. Li, F. Zhao, H. Gao, Hydrothermal preparation of Fe2O3/graphene nanocomposite and its enhanced catalytic activity on the thermal decomposition of ammonium perchlorate. Appl. Surf. Sci. 303, 354–359 (2014)
Y. Zu, Y. Zhao, K. Xu, T. Yao, F. Zhao, Preparation and comparison of catalytic performance for nano MgFe2O4, GO-loaded MgFe2O4 and GO-coated MgFe2O4 nanocomposites. Ceram. Int. 42, 1–7 (2016)
J.Y. Yu, J.H. Wang, Y.C. Liu, Y.W. Yu, J.M. Yuan, S.M. Jing, Preparation and thermal properties of CL-20/GO nano-composite energetic materials. Sci. Technol. Eng. 17, 93–96 (2017)
J.L. Sabourin, D.M. Dabbs, R.A. Yetter, F.L. Dryer, I.A. Aksay, Functionalized graphene sheet colloids for enhanced fuel/propellant combustion. ACS Nano 3, 3945 (2009)
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Zhu, Y., Fu, X., Su, J., Hu, Y., Wu, L. (2022). Review of Graphene-Based Energetic Compounds. In: Gany, A., Fu, X. (eds) 2021 International Conference on Development and Application of Carbon Nanomaterials in Energetic Materials. ICCN 2021. Springer Proceedings in Physics, vol 276. Springer, Singapore. https://doi.org/10.1007/978-981-19-1774-5_34
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DOI: https://doi.org/10.1007/978-981-19-1774-5_34
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