Abstract
Rare and precious metals materials with unique physical and chemical properties are widely used in aviation, aerospace, navigation, electronic, electric, petroleum chemical industry, glass fiber, waste gas purification, metallurgical and other industries, which are known as “the vitamin of modern industry”. In this article, the development and application of Pt–Au–Sn system, the binary and ternary alloy phase diagrams in the Pt–Au–Sn system, and the related thermodynamic parameters, including phase structure and formation enthalpy of alloy, the cohesive energy and the Gibbs free energy of Pt–Au–Sn system were reviewed, at the same time, the further research interests and the experimental verification of phase diagram of Pt–Au–Sn system were also discussed, which could provide necessary theoretical support for the alloy composition design and industrial applications in the future.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
References
C. Xu, Y. Xu, Y. Yang et al., Au/Sn eutectic bonding technology in the application of MEMS packaging. Micro Nanoelectronic Technol. 51, 131–135 (2014)
J. Ma, H. Sun, H. Z et al., Electrocatalytic performance of carbon supported Pt-Sn catalyst prepared with direct thermo-decomposition method for ethanol oxidation. Chem. J. Chin. Univ. 32, 2856–2860 (2011)
J. Cai, F. Yang, K. Qiu et al., Novel electrical contact materials Ag/La1–xSrxCoO3. Electron. Compon. Mater. 33, 1–3 (2014)
W. L, Y. Huang, Y. Ma, Research progress in preparation and application of Au80Sn20 solder alloy. Mater. Rev. 27, 1–6 (2013)
H. Oppermann, E. Zschech, C. Whelan et al., Materials for Information Technology (Springer, London, 2005), pp. 377–390
G.S. Zhang, H.Y. Jing, L.Y. Xu et al., Creep behavior of eutectic 80Au/20Sn solder alloy. J. Alloys Compd. 476, 138–141 (2009)
L. Wang, Y. Wang, W. Liao et al., Ethanol electrocatalytic oxidation performance of carbon black-supported Pt-Sn bimetallic catalysts. J. Mol. Catal. 39, 35–44 (2014)
Z. Chen, D. Chen, J. Qin et al., Electrocatalytic effect of polyaniline electrode modified by platinum microparticles on oxidation of formaldehyde. Mater. Rev. 28, 36–39 (2014)
S. Sun, P. Mu, Influence of nafion and the proportion of water and isopropyl alcohol on activity of Pt/C catalyst. Mater. Rev. 28, 36–39 (2014)
X. Ma, X. Ge, Q. Yuan, Research of direct methanol fuel cell catalysts. Sci. Technol. Vision 14, 101–102 (2015)
J. Li, X. Wang, L. Yi et al., Research of Au-based anode electrocatalysts materials and reaction mechanism for direct borohydride fuel cell. Chin. J. Power Sources 38, 181–184 (2014)
L. Liu, D. Fang, W. Ren et al., Preparation of Au-Pt-Sn catalysts for isobutane dehydrogenation. Ind. Catal. 22, 293–296 (2014)
L. Liu, Phase Diagram Thermodynamic Calculation and Experimental Study of Au-Pd-Zr Ternary Alloy (Kunming University of Science and Technology, Kunming, 2011)
Y. Wu, Thermodynamic Optimization and Calculation of Pt-Zr-X (X=Ir, Au) System (Kunming University of Science and Technology, Kunming, 2014)
X. Su, F. Yin, M. Huang, Z. Li, C. Chen, J. Alloys Compd. 325, 109–112 (2001)
S.-L. Chen, S. Daniel, F. Zhang, Y.A. Chang, W.A. Oates, R. Schmid-Fetzer, J. Phase Equilib. Diff. 22, 373–378 (2001)
R. Schmid-Fetzer, A. Kozlov, Thermodynamic aspects of grain growth restriction in multicomponent alloy solidification. Acta Mater. 59, 6133–6144 (2011)
G. Vincent, S.F. Rainer, Thermodynamic analysis of the Pt–Sn system. J. Alloy. Compd. 450, 264–271 (2008)
A.T. Dinsdale, Calphad 15(4), 317–425 (1991)
R. Schmid, Y.A. Chang, Calphad 9(4), 363–382 (1985)
W. Zhou, L. Liu, B. Li et al., Structural, elastic and electronic properties of intermetallics in the Pt–Sn system: a density functional investigation. Comput. Mater. Sci. 46, 921–931 (2009)
K.L. Shelton, P.A. Merewether, B.J. Skinner, Phases and phase relations in the system Pd-Pt-Sn. Can. Mineral 19, 599–605 (1981)
J.S. Charlton, H.M. Cordey, I.R. Harris, A study of the 119Sn Moessbauer isomer shifts in some platinum-tin and gold-tin alloys. J. Less-Common Metals 20, 105–112 (1970)
K. Schubert, H. Pfisterer, Die Kristallstruktur von Pt2Sn3. Z. Metallkd. 40, 105–112 (1949)
F. Doerinckel, Z. Anorg. Chem. 54, 333–366 (1907)
P.H. Durussel, R. Massara, P. Feschotte, J. Alloy. Compd. 215, 175–179 (1994)
P. Anres, M. Gaune-Escard, J.P. Bros, E. Hayer, J. Alloy. Compd. 280, 158–167 (1998)
J.S. Charlton, M. Cordey-Hayes, I.R. Harris, A study of the 119Sn mössbauer isomer shifts in some platinum-tin and gold-tin alloys. J. Les. Comm. Met. 20, 105–112 (1970)
U.C. Rodewald, R.D. Hoffmann, Z. Wu et al., Structure refinement of AuSn2. Z. Naturforsch. 61, 108–110 (2006)
P.Y. Chevalier, A thermodynamic evaluation of the Au-Sn system. Thermochim. Acta 130, 1–13 (1988)
L.C. Liu, H.S. Liu, K. Ishida et al., Thermodynamic modeling of the Au-In-Sn system. J. Electron. Mater. 32, 1290–1296 (2003)
V. Grolier, R.F. Schmid, Experimental study of Au-Pt-Sn phase equilibria and thermodynamic assessment of the Au-Pt and Au-Pt-Sn systems. J. Electron. Mater. 37, 264–278 (2008)
A. Jena, M. Bever, On the thermodynamic properties of the phases Zeta and AuSn in the system Au-Sn. Metall. Mater. Trans. B 10, 545–549 (1979)
H. Dong, Thermodynamic Optimization and Calculation of Au-Sn-X(X=Co, La, Er) System (Central South University, Chamgsha, 2010)
A. Dębski, W. Gąsior, Z. Moser, R. Major, Enthalpy of formation of intermetallic phases from the Au-Sn system. J. Alloy. Compd. 491, 173–177 (2010)
J. Hu, M. Xie, J. Zhang et al., First principles study of Au-Sn intermetallic compounds. Acta Phys. Sinica 62, 247102 (2013)
X. Xu, Y. Ren, C. Li et al., Thermodynamic assessment of Au–Pt system. Trans. Nonferrous Metals Soc. China 22, 1432–1436 (2012)
N.T. Alexandra, O. Laila, A. Kjekshus et al., The tin-rich part of the Au-Pt-Sn system. J. Alloys Compd. 314, 92–95 (2001)
H. Dong, V. Vuorinen, M. Broas, M. Paulasto-Kr€ockel, Thermodynamic reassessment of the Au-Pt-Sn system and microstructural evolution of the (AuSn)eut-Pt interconnection. J. Alloy. Compd. 688, 388–398 (2016)
Acknowledgements
This work was financially supported by the Nature Science Foundation of China (U1602275, U1602271, U1302272, 51267007, 51461023, 51507075); Institutes Special Technology Development Project of Yunnan (2013DC016); Fund of the Collaborative Innovation Center of Rare and Precious Metals Advanced Materials (2014XT02). Finally, we also wish to thank referee for useful suggestions and comments.
Author information
Authors and Affiliations
Corresponding author
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2018 Springer Nature Singapore Pte Ltd.
About this paper
Cite this paper
Hu, J., Xie, M., Chen, S., Li, A., Wang, S., Chen, Y. (2018). An Overview of Phase Diagram and Thermodynamic Parameters of Pt–Au–Sn System. In: Han, Y. (eds) Advances in Materials Processing. CMC 2017. Lecture Notes in Mechanical Engineering. Springer, Singapore. https://doi.org/10.1007/978-981-13-0107-0_86
Download citation
DOI: https://doi.org/10.1007/978-981-13-0107-0_86
Published:
Publisher Name: Springer, Singapore
Print ISBN: 978-981-13-0106-3
Online ISBN: 978-981-13-0107-0
eBook Packages: EngineeringEngineering (R0)