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An Overview of Phase Diagram and Thermodynamic Parameters of Pt–Au–Sn System

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Advances in Materials Processing (CMC 2017)

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Abstract

Rare and precious metals materials with unique physical and chemical properties are widely used in aviation, aerospace, navigation, electronic, electric, petroleum chemical industry, glass fiber, waste gas purification, metallurgical and other industries, which are known as “the vitamin of modern industry”. In this article, the development and application of Pt–Au–Sn system, the binary and ternary alloy phase diagrams in the Pt–Au–Sn system, and the related thermodynamic parameters, including phase structure and formation enthalpy of alloy, the cohesive energy and the Gibbs free energy of Pt–Au–Sn system were reviewed, at the same time, the further research interests and the experimental verification of phase diagram of Pt–Au–Sn system were also discussed, which could provide necessary theoretical support for the alloy composition design and industrial applications in the future.

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References

  1. C. Xu, Y. Xu, Y. Yang et al., Au/Sn eutectic bonding technology in the application of MEMS packaging. Micro Nanoelectronic Technol. 51, 131–135 (2014)

    CAS  Google Scholar 

  2. J. Ma, H. Sun, H. Z et al., Electrocatalytic performance of carbon supported Pt-Sn catalyst prepared with direct thermo-decomposition method for ethanol oxidation. Chem. J. Chin. Univ. 32, 2856–2860 (2011)

    CAS  Google Scholar 

  3. J. Cai, F. Yang, K. Qiu et al., Novel electrical contact materials Ag/La1–xSrxCoO3. Electron. Compon. Mater. 33, 1–3 (2014)

    Google Scholar 

  4. W. L, Y. Huang, Y. Ma, Research progress in preparation and application of Au80Sn20 solder alloy. Mater. Rev. 27, 1–6 (2013)

    Google Scholar 

  5. H. Oppermann, E. Zschech, C. Whelan et al., Materials for Information Technology (Springer, London, 2005), pp. 377–390

    Book  Google Scholar 

  6. G.S. Zhang, H.Y. Jing, L.Y. Xu et al., Creep behavior of eutectic 80Au/20Sn solder alloy. J. Alloys Compd. 476, 138–141 (2009)

    Article  CAS  Google Scholar 

  7. L. Wang, Y. Wang, W. Liao et al., Ethanol electrocatalytic oxidation performance of carbon black-supported Pt-Sn bimetallic catalysts. J. Mol. Catal. 39, 35–44 (2014)

    Google Scholar 

  8. Z. Chen, D. Chen, J. Qin et al., Electrocatalytic effect of polyaniline electrode modified by platinum microparticles on oxidation of formaldehyde. Mater. Rev. 28, 36–39 (2014)

    Google Scholar 

  9. S. Sun, P. Mu, Influence of nafion and the proportion of water and isopropyl alcohol on activity of Pt/C catalyst. Mater. Rev. 28, 36–39 (2014)

    Google Scholar 

  10. X. Ma, X. Ge, Q. Yuan, Research of direct methanol fuel cell catalysts. Sci. Technol. Vision 14, 101–102 (2015)

    Google Scholar 

  11. J. Li, X. Wang, L. Yi et al., Research of Au-based anode electrocatalysts materials and reaction mechanism for direct borohydride fuel cell. Chin. J. Power Sources 38, 181–184 (2014)

    CAS  Google Scholar 

  12. L. Liu, D. Fang, W. Ren et al., Preparation of Au-Pt-Sn catalysts for isobutane dehydrogenation. Ind. Catal. 22, 293–296 (2014)

    CAS  Google Scholar 

  13. L. Liu, Phase Diagram Thermodynamic Calculation and Experimental Study of Au-Pd-Zr Ternary Alloy (Kunming University of Science and Technology, Kunming, 2011)

    Google Scholar 

  14. Y. Wu, Thermodynamic Optimization and Calculation of Pt-Zr-X (X=Ir, Au) System (Kunming University of Science and Technology, Kunming, 2014)

    Google Scholar 

  15. X. Su, F. Yin, M. Huang, Z. Li, C. Chen, J. Alloys Compd. 325, 109–112 (2001)

    Article  CAS  Google Scholar 

  16. S.-L. Chen, S. Daniel, F. Zhang, Y.A. Chang, W.A. Oates, R. Schmid-Fetzer, J. Phase Equilib. Diff. 22, 373–378 (2001)

    Article  CAS  Google Scholar 

  17. R. Schmid-Fetzer, A. Kozlov, Thermodynamic aspects of grain growth restriction in multicomponent alloy solidification. Acta Mater. 59, 6133–6144 (2011)

    Article  CAS  Google Scholar 

  18. G. Vincent, S.F. Rainer, Thermodynamic analysis of the Pt–Sn system. J. Alloy. Compd. 450, 264–271 (2008)

    Article  CAS  Google Scholar 

  19. A.T. Dinsdale, Calphad 15(4), 317–425 (1991)

    Article  CAS  Google Scholar 

  20. R. Schmid, Y.A. Chang, Calphad 9(4), 363–382 (1985)

    Article  CAS  Google Scholar 

  21. W. Zhou, L. Liu, B. Li et al., Structural, elastic and electronic properties of intermetallics in the Pt–Sn system: a density functional investigation. Comput. Mater. Sci. 46, 921–931 (2009)

    Article  CAS  Google Scholar 

  22. K.L. Shelton, P.A. Merewether, B.J. Skinner, Phases and phase relations in the system Pd-Pt-Sn. Can. Mineral 19, 599–605 (1981)

    CAS  Google Scholar 

  23. J.S. Charlton, H.M. Cordey, I.R. Harris, A study of the 119Sn Moessbauer isomer shifts in some platinum-tin and gold-tin alloys. J. Less-Common Metals 20, 105–112 (1970)

    Article  CAS  Google Scholar 

  24. K. Schubert, H. Pfisterer, Die Kristallstruktur von Pt2Sn3. Z. Metallkd. 40, 105–112 (1949)

    Google Scholar 

  25. F. Doerinckel, Z. Anorg. Chem. 54, 333–366 (1907)

    Article  CAS  Google Scholar 

  26. P.H. Durussel, R. Massara, P. Feschotte, J. Alloy. Compd. 215, 175–179 (1994)

    Article  CAS  Google Scholar 

  27. P. Anres, M. Gaune-Escard, J.P. Bros, E. Hayer, J. Alloy. Compd. 280, 158–167 (1998)

    Article  CAS  Google Scholar 

  28. J.S. Charlton, M. Cordey-Hayes, I.R. Harris, A study of the 119Sn mössbauer isomer shifts in some platinum-tin and gold-tin alloys. J. Les. Comm. Met. 20, 105–112 (1970)

    Article  CAS  Google Scholar 

  29. U.C. Rodewald, R.D. Hoffmann, Z. Wu et al., Structure refinement of AuSn2. Z. Naturforsch. 61, 108–110 (2006)

    Article  CAS  Google Scholar 

  30. P.Y. Chevalier, A thermodynamic evaluation of the Au-Sn system. Thermochim. Acta 130, 1–13 (1988)

    Article  CAS  Google Scholar 

  31. L.C. Liu, H.S. Liu, K. Ishida et al., Thermodynamic modeling of the Au-In-Sn system. J. Electron. Mater. 32, 1290–1296 (2003)

    Article  CAS  Google Scholar 

  32. V. Grolier, R.F. Schmid, Experimental study of Au-Pt-Sn phase equilibria and thermodynamic assessment of the Au-Pt and Au-Pt-Sn systems. J. Electron. Mater. 37, 264–278 (2008)

    Article  CAS  Google Scholar 

  33. A. Jena, M. Bever, On the thermodynamic properties of the phases Zeta and AuSn in the system Au-Sn. Metall. Mater. Trans. B 10, 545–549 (1979)

    Article  Google Scholar 

  34. H. Dong, Thermodynamic Optimization and Calculation of Au-Sn-X(X=Co, La, Er) System (Central South University, Chamgsha, 2010)

    Google Scholar 

  35. A. Dębski, W. Gąsior, Z. Moser, R. Major, Enthalpy of formation of intermetallic phases from the Au-Sn system. J. Alloy. Compd. 491, 173–177 (2010)

    Article  CAS  Google Scholar 

  36. J. Hu, M. Xie, J. Zhang et al., First principles study of Au-Sn intermetallic compounds. Acta Phys. Sinica 62, 247102 (2013)

    Google Scholar 

  37. X. Xu, Y. Ren, C. Li et al., Thermodynamic assessment of Au–Pt system. Trans. Nonferrous Metals Soc. China 22, 1432–1436 (2012)

    Article  CAS  Google Scholar 

  38. N.T. Alexandra, O. Laila, A. Kjekshus et al., The tin-rich part of the Au-Pt-Sn system. J. Alloys Compd. 314, 92–95 (2001)

    Google Scholar 

  39. H. Dong, V. Vuorinen, M. Broas, M. Paulasto-Kr€ockel, Thermodynamic reassessment of the Au-Pt-Sn system and microstructural evolution of the (AuSn)eut-Pt interconnection. J. Alloy. Compd. 688, 388–398 (2016)

    Article  CAS  Google Scholar 

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Acknowledgements

This work was financially supported by the Nature Science Foundation of China (U1602275, U1602271, U1302272, 51267007, 51461023, 51507075); Institutes Special Technology Development Project of Yunnan (2013DC016); Fund of the Collaborative Innovation Center of Rare and Precious Metals Advanced Materials (2014XT02). Finally, we also wish to thank referee for useful suggestions and comments.

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Correspondence to Ming Xie .

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Hu, J., Xie, M., Chen, S., Li, A., Wang, S., Chen, Y. (2018). An Overview of Phase Diagram and Thermodynamic Parameters of Pt–Au–Sn System. In: Han, Y. (eds) Advances in Materials Processing. CMC 2017. Lecture Notes in Mechanical Engineering. Springer, Singapore. https://doi.org/10.1007/978-981-13-0107-0_86

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  • DOI: https://doi.org/10.1007/978-981-13-0107-0_86

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