Abstract
Sulfate in Zhundong (ZD) coal combustion plays a significant role in fouling, slagging, and particle emissions. This study aimed to investigate the effect of SiO2 and kaolin addition on sulfate transformation in ZD coal ash by using thermogravimetric analysis (TGA) and other characterizing methods for ash with SiO2 and kaolin addition under different temperatures. Results showed that SiO2 and kaolin both enhanced the decomposition of sulfates in ZD coal ash under higher temperatures. The decomposition of sulfates in pure ZD coal ash started above 1050 °C, while the starting temperature was ahead by 50 and 100 °C, when SiO2 and kaolin were added, respectively. Kaolin addition was more efficient to improve the thermal decomposition of sulfates than SiO2 addition. However, the enhanced effect of SiO2 and kaolin was very weak below 815 °C. The thermal calculation results also gave the similar result on the enhancement effect on sulfate decomposition of SiO2 and kaolin addition.
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References
Zhang S, Chen C, Shi D (2013) Situation of combustion utilization of high sodium coal. Proc CSEE 33(5):1–13
Dai B, Low F, Girolamo A (2013) Characteristics of ash deposits in a pulverized lignite coal-fired boiler and the mass flow of major ash-forming inorganic elements. Energy Fuels 27(10):6198–6211
Zhou H, Zhou B, Li L (2013) experimental measurement of the effective thermal conductivity of ash deposit for high sodium coal (Zhun Dong coal) in a 300 KW test furnace. Energy Fuels 27(11):7008–7022
Yang Z, Liu J, Yao W (2013) Fouling index of Zhundong coal ash. Clean Coal Technol 19(2):81–84
Wang X, Xu Z, Wei B (2015) The ash deposition mechanism in boilers burning Zhundong coal with high contents of sodium and calcium: a study from ash evaporating to condensing. Appl Therm Eng 80:150–159
Wang X, Xu Z, Wei B et al (2015) The ash deposition mechanism in boilers burning Zhundong coal with high contents of sodium and calcium: a study from ash evaporating to condensing. Appl Therm Eng 80:150–159
Acknowledgments
This study was supported by the National Natural Science Foundation of China (Nos. 51306142 and 51376147) and the Fundamental Research Funds for the Central Universities.
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© 2016 Springer Science+Business Media Singapore and Tsinghua University Press
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Wang, X., Wu, H., Deng, S., Zhang, L., Wei, B., Tan, H. (2016). A Mechanism Study on the Decomposition of Sulfate in Zhundong Coal with High Sulfur Content in Coal Ash. In: Yue, G., Li, S. (eds) Clean Coal Technology and Sustainable Development. ISCC 2015. Springer, Singapore. https://doi.org/10.1007/978-981-10-2023-0_14
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DOI: https://doi.org/10.1007/978-981-10-2023-0_14
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