Abstract
Limestone calcined-clay cements (LC3) take advantage of the synergetic effects of calcium carbonate reaction with the additional aluminium provided by the calcined clay. As temperature decreases, calcium carbonate solubility increase, therefore, the early-age hydration kinetics and the optimal proportioning of the ternary cement system are modified. This study explored the reactivity and mechanical performance of different LC3 systems cured at 10 and 20 ºC. Mixtures containing PC, PC-limestone and a LC3 blends with 50% clinker factors and 2:1 clay-to-limestone ratio were cast and compared. Hydration kinetics were assessed using isothermal calorimetry at each of the temperatures. The evolution of porosity was studied during hydration by MIP. Compressive strength was measured over time on cement paste cubes. Phase assemblage was monitored using XRD.
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References
Schneider, M., Romer, M., Tschudin, M., Bolio, H.: Sustainable cement production—present and future. Cem. Concr. Res. 41, 642–650 (2011). doi:10.1016/j.cemconres.2011.03.019
Lara, R.C., Antoni, M., Díaz, A.A., Scrivener, K., Fernando, J., Hernández, M.: Estudio de la adición de arcillas calcinadas en la durabilidad de hormigones. Rev. Ing. Construcción. 26, 25–40 (2011)
Lothenbach, B., Scrivener, K., Hooton, R.D.: Supplementary cementitious materials. Cem. Concr. Res. 41, 1244–1256 (2011). doi:10.1016/j.cemconres.2010.12.001
Jain, N.: Effect of nonpozzolanic and pozzolanic mineral admixtures on the hydration behavior of ordinary Portland cement. Constr. Build. Mater. 27, 39–44 (2012). doi:10.1016/j.conbuildmat.2011.08.006
Karim, E., El-Hadj, K., Abdelkader, B., Rachid, B.: Analysis of mortar long-term strength with supplementary cementitious materials cured at different temperatures. ACI Mater. J. 107, 323–331 (2010)
Mehta, P.: Durability - critical issues for the future. Concr. Int. 19, 69–76 (1997)
Schneider, M., Romer, M., Tschudin, M., Bolio, H.: Sustainable cement production—present and future. Cem. Concr. Res. 41, 642–650 (2011). doi:10.1016/j.cemconres.2011.03.019
Taylor, H.F.W.: Cement Chemistry, 2nd edn. Thomas Telford, London (1997)
Bentz, D.P., Sato, T., De La Varga, I., Weiss, W.J.: Fine limestone additions to regulate setting in high volume fly ash mixtures. Cem. Concr. Compos. 34, 11–17 (2012). doi:10.1016/j.cemconcomp.2011.09.004
Tironi, A., Trezza, M.A., Scian, A.N., Irassar, E.F.: Assessment of pozzolanic activity of different calcined clays. Cem. Concr. Compos. 37, 319–327 (2013). doi:10.1016/j.cemconcomp.2013.01.002
Fernandez, R., Martirena, F., Scrivener, K.L.: The origin of the pozzolanic activity of calcined clay minerals: a comparison between kaolinite, illite and montmorillonite. Cem. Concr. Res. 41, 113–122 (2011). doi:10.1016/j.cemconres.2010.09.013
Bentz, D.P., Ferraris, C.F., Jones, S.Z., Lootens, D., Zunino, F.: Limestone and silica powder replacements for cement: early-age performance. Cem. Concr. Compos. 78, 43–56 (2017). doi:10.1016/j.cemconcomp.2017.01.001
Matschei, T., Lothenbach, B., Glasser, F.P.: The AFm phase in Portland cement. Cem. Concr. Res. 37, 118–130 (2007). doi:10.1016/j.cemconres.2006.10.010
Chowaniec, O.: Limestone Addition in Cement (2012). https://infoscience.epfl.ch/record/174700
Bentz, D.P., Stutzman, P.E., Zunino, F.: Low-temperature curing strength enhancement in cement-based materials containing limestone powder. Mater. Struct. 50, pii:173 (2017)
Avet, F., Snellings, R., Alujas Diaz, A., Ben Haha, M., Scrivener, K.: Development of a new rapid, relevant and reliable (R3) test method to evaluate the pozzolanic reactivity of calcined kaolinitic clays. Cem. Concr. Res. 85, 1–11 (2016). doi:10.1016/j.cemconres.2016.02.015
Antoni, M., Rossen, J., Martirena, F., Scrivener, K.: Cement substitution by a combination of metakaolin and limestone. Cem. Concr. Res. 42, 1579–1589 (2012). doi:10.1016/j.cemconres.2012.09.006
Gallucci, E., Zhang, X., Scrivener, K.L.: Effect of temperature on the microstructure of calcium silicate hydrate (C-S-H). Cem. Concr. Res. 53, 185–195 (2013). doi:10.1016/j.cemconres.2013.06.008
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Authors acknowledge funding provided by the Swiss commission for scholarships for foreign students (FCS), through their Ph.D. scholarship program.
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Zunino, F., Scrivener, K. (2018). Reactivity and Performance of Limestone Calcined-Clay Cement (LC3) Cured at Low Temperature. In: Martirena, F., Favier, A., Scrivener, K. (eds) Calcined Clays for Sustainable Concrete. RILEM Bookseries, vol 16. Springer, Dordrecht. https://doi.org/10.1007/978-94-024-1207-9_82
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DOI: https://doi.org/10.1007/978-94-024-1207-9_82
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