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Electron Spin Resonance Spectroscopy

Generalized Spin-Peierls Transition in Carbynoid Films

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Carbyne and Carbynoid Structures

Part of the book series: Physics and Chemistry of Materials with Low-Dimensional Structures ((PCMALS,volume 21))

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Abstract

Some ideas of generalized Peierls as well generalized spin-Peierls (s-P) transitions in conjugated (quasi) 1D—polymers are discussed. ESR, IR and microwave photoconductivity studies on oriented carbynoid samples prepared by chemical dehydrofluorination of poly(vinylidene fluoride) (PVDF) agreed rather well with the assuption of a room temperature generalized S-P system. Concepts of s-P solitons and s-P soliton lattice formation in carbynoid films at room temperature are proposed and discussed.

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Authors and Affiliations

  1. Department of Physics, Byelorussian State University, Minsk, Russia

    D. P. Ertchak

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  1. D. P. Ertchak
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Editors and Affiliations

  1. Department of Mineralogy, Freiberg University of Mining and Technology, Freiberg, Germany

    Robert B. Heimann

  2. A.N. Nesmeyanov Institute of Organo-Element Compounds, The Russian Academy of Sciences, Moscow, Russia

    Sergey E. Evsyukov

  3. J. Heyrovsky Institute of Physical Chemistry, Prague, Czech Republic

    Ladislav Kavan

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Ertchak, D.P. (1999). Electron Spin Resonance Spectroscopy. In: Heimann, R.B., Evsyukov, S.E., Kavan, L. (eds) Carbyne and Carbynoid Structures. Physics and Chemistry of Materials with Low-Dimensional Structures, vol 21. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-4742-2_24

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  • DOI: https://doi.org/10.1007/978-94-011-4742-2_24

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-94-010-5993-0

  • Online ISBN: 978-94-011-4742-2

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