Abstract
In order to understand the behaviour of polymeric materials for use as matrices in fibre reinforced composites and structural adhesives it is necessary to determine the fracture mechanisms of such polymers not only in the bulk form but also in the form anticipated for their expected use. Even if the resin displays excellent properties in bulk form, they may not be translated to laminated composites. This has been demonstrated by Bersch [1] who identified 24 polymers which show higher strains to failure than current epoxies. However, only five of those resins under investigation provided a higher strain to failure when contained in a composite system, as examined by the residual compression strength after impact technique. Further evidence of the inability to read across information into the composite system was provided by other shortcomings in properties, especially the elastic modulus, which rendered many of the polymers unsuitable for use as matrices in a composite system. Other attempts have been made to improve the composite toughness by improving the toughness of the polymer systems. These also have had disappointing results, in that a large increase in polymer toughness has not necessarily been found to give a proportionate increase in composite toughness.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
Bersch, C. F. (1982) What we have done. Proc. Critical Review: Techniques for Characterisation of Composite Materials, Army Materials and Mechanics Research Centre, MA. AMMRC MS Report 82-3, pp. 487–9.
Scott, J. M. and Phillips, D. C. (1975) Carbon fibre composites with rubber toughened matrices. Journal of Materials Science, 10, 551–62.
Bascom, W. D, Bitner, J. L, Moulton, R. J. and Siebart, A. R. (1980) The inter-laminar fracture of organic-matrix, woven reinforcement composites. Composites, 1, 9–18.
Bascom, W. D, Ting, R. Y, Moulton, R. J, Riew, C. K. and Siebart, A. R. (1981) The fracture of an epoxy composite containing elastomeric modifiers. Journal of Materials Science, 16, 2657–64.
Vanderkley, P. S. (1981) Mark I-mode II delamination fracture toughness of a uni-directional graphite/epoxy composite. Masters Thesis, Texas A & M University, College Station, TX, December 1981.
Cohen, R. N. (1982) Effect of resin toughness on fracture behaviour of graphite/epoxy composites. Masters Thesis, Texas A & M University, College Station, TX, December 1982.
Bradley, W. L. and Cohen, R. N. (1983) Matrix deformation and fracture in graphite reinforced epoxies. ASTM Symposium — Delamination and Debonding of Materials, Pittsburgh, PA, November 8–10, 1983.
Kanninen, M. F, Rybicki, E. F. and Brinson, H. F. (1977) A critical look at current applications of fracture mechanics to the failure of fibre reinforced composites. Composites, 1, 17–22.
Wang, S. S., Chin, E. S., Yu, T. P. and Goetz, D. P. (1983) Fracture of random short fibre SMC composite. Journal of Composite Materials, 17, 299–315.
Folkes, M. J. (1982) Short Fibre Reinforced Plastics, Research Studies Press, Wiley, New York.
Blumentritt, B. F., Vu, B. T. and Cooper, S. L. (1975) Fracture in orientated short fibre reinforced thermoplastics. Composites, 5, 105–14.
Harris, B. (1986) Engineering Composite Materials, Institute of Metals.
Cooper, G. A. (1970) The fracture toughness of composites reinforced with weakened fibres. Journal of Materials Science, 5, 645–54.
Piggot, M. R. (1970) Theoretical estimation of fracture toughness of fibrous composites. Journal of Materials Science, 5, 669–75.
McGrath, G. C. (1988) Structure and properties of carbon fibre reinforced aromatic thermoplastics. PhD Thesis, Sheffield City Polytechnic.
Barlow, C. Y., Ward, M. V. and Windle, A. H. (1985) The influence of microstructure on the toughness of carbon fibre/plastic composites. Proceedings 6th International Conference on Deformation Yield and Fracture of Polymers, April 1985, pp. 14.1–14.4.
Chai, H. (1984) The characterisation of mode I delamination failure in non woven, multi-directional laminates. Composites, 15, 277–90.
Greenhalgh, E. S. and McGrath, G. C. (1991) Fracture analysis of thermoplastic welds. 1st International Conference on Deformation and Fracture of Composites, Manchester, March 25–27, 1991.
Wang, S. S., Suemasu, H. and Zahlan, N. M. (1984) Interlaminar fracture of random short fibre SMC composite. Journal of Composite Materials, 18, 574–94.
Rayson, H. W., McGrath, G. C. and Collyer, A.A. (1986) Fibres, whiskers and flakes for composite applications, in Mechanical Properties of Reinforced Thermoplastics (eds D. W. Clegg and A. A. Collyer), Applied Science, London, Chapter 2.
Jones, R. M. (1975) Mechanics of Composite Materials, McGraw-Hill, New York.
Ashton, J. E., Halpin, J. E. and Petit, P. H. (1969) Primer on Composite Materials: Analysis, Technomic, Stamford, CT.
Greaves, L. J. (1987) Stiffness matrices of a carbon fibre cloth laminate. RAE Technical Report 87047.
Reifsnider, K. L. and Talung, A. (1980) Analysis of fatigue damage in composite laminates. International Journal of Fatigue, 2, 3–11.
Reifsnider, K. L. and Highsmith, A. (1981) Advances in fracture research. ICF5, Cannes, Vol. 1.
Reifsnider, K. L. and Jamison, R. (1982) Fracture of fatigue-loaded composite laminates. International Journal of Fatigue, 4, 187–97.
Boniface, L. and Bader, M. G. (1986) The micromechanics of damage initiation and development under static and fatigue loading of CFRP XAS/914 and E-glass laminates. D/ERI/9/4/2064/066 XR/MAT.
Reifsnider, K. L., Henneke, E. G., Stinchcomb, W. and Duke, J. C. (1983) Damage mechanics and NDE of composite laminates. Mechanics of Composite Materials, Recent Advances, 19, 399–420.
Rosen, B. W. (1964) Tensile failures of fibrous composites. AIAA Journal, 2, 1985–91.
Zweben, C. (1968) Tensile failures of fibrous composites. AIAA Journal, 6, 2325–31.
Curtis, P. T. (1986) A comparison of the mechanical properties of improved carbon fibre composite materials. RAE TR 86021.
Talreja, R. (1981) Fatigue of composite materials: damage mechanisms and fatigue life diagrams. Proceedings of the Royal Society of London, Series A, 378(1775), 461–75.
Bailey, J. E. and Parvizi, A. (1981) On fibre debonding effects and the mechanism of transverse-ply failure in cross ply laminates of glass fibre/thermoset composites. Journal of Materials Science, 16, 649–59.
Bailey, J. E., Curtis, P. T. and Parvizi, A. (1979) Proceedings of the Royal Society of London, Series A, 366, 599–623.
Hashin, Z. (1985) Analysis of cracked laminates: a variational approach. Mechanics of Materials, 4, 121–36.
Ogin, S. L. and Smith, P. A. (1987) A model for matrix cracking in cross-ply laminates. ESA Journal, 11, 45–60.
Griffith, A. A. (1921) The phenomena of rupture and flow in solids. Philosophical Transactions of the Royal Society of London, Series A, 221, 163–98.
Berry, J. P. (1961) Fracture processes in polymeric materials: I. The surface energy of polymethylmethacrylate. Journal of Polymer Science, 50, 107–15.
Whitney, J. M., Browning, C. E. and Hoogsteder, W. (1982) A double cantilever beam test for characterising mode one delamination of composite materials. Journal of Reinforced Plastics and Composites, 1, 297–313.
Hartness, J. T. (1982) Polyetheretherketone matrix composites. 14th National SAMPE Technical Conference, October 12–14, 1982, pp. 26–37.
Carlile, D. R. and Leach, D. C. (1983) Damage and notch sensitivity of graphite/PEEK composites. 15th National SAMPE Technical Conference, October 1983, pp. 82–93.
Donaldson, S. L. (1985) Fracture toughness testing of graphite/epoxy and graphite/PEEK composites. Composites, 16(2), 103–12.
Blundell, D. J. and Osborn, B. N. (1983) The morphology of poly(aryl-ether-ether-ketone). Polymer, 24, 953–58.
Irwin, G. R. (1957) Analysis of stresses and strains near the end of a crack traversing a plate. Journal of Applied Mechanics, 24, 361–4.
Timoshenko, S. D. (1955) Strength of Materials, Part 1, 3rd edn, Van Nostrand, New York.
Devitt, D. F., Schapery, R. A. and Bradley, W. L. (1980) A method for determining the mode I delamination fracture toughness of elastic and viscoelastic composite materials. Journal of Composite Materials, 14, 270–85.
Crandall, S. H. (1956) Engineering Analysis, McGraw-Hill, New York.
Barlow, C. Y. and Windle, A. H. (1985) Razor blade test for composites toughness. Journal of Materials Science Letters, 4, 233–4.
Williams, J. G. (1987) Large displacements and end block effects in the DCB interlaminar test in modes I and II. Journal of Composite Materials, 21, 330–48.
Williams, J. G. (1987) Large displacement effects in the DCB test for interlaminar fracture in modes I and II. Proc. ICC MVI/ECCM, Vol. 3, Applied Science, Barking, pp. 233–42.
Williams, J. G. (1989) End corrections for orthotropic DCB specimens. Composite Science and Technology, 35, 367–79.
Hashemi, S., Kinloch, A. J. and Williams, J. G. (1990) The effects of geometry, rate and temperature on the mode I, mode II and mixed mode I/II interlaminar fracture of carbon-fibre/polyetheretherketone composites. Journal of Composite Materials, 24, 918–56.
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1994 Springer Science+Business Media Dordrecht
About this chapter
Cite this chapter
McGrath, G.C. (1994). Fracture and toughening in fibre reinforced polymer composites. In: Collyer, A.A. (eds) Rubber Toughened Engineering Plastics. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-1260-4_3
Download citation
DOI: https://doi.org/10.1007/978-94-011-1260-4_3
Publisher Name: Springer, Dordrecht
Print ISBN: 978-94-010-4549-0
Online ISBN: 978-94-011-1260-4
eBook Packages: Springer Book Archive