Skip to main content
SpringerLink
Log in

The Dynamics of Anion Solvation in Alcohols

  • Chapter
Ultrafast Dynamics of Chemical Systems

Part of the book series: Understanding Chemical Reactivity ((UCRE,volume 7))

Abstract

The importance of the solvent in chemical reactivity has been long recognized,1 albeit the quantification of the various roles that the solvent can play was not possible. These roles include: supplying or dissipating energy by acting as a heat bath, confining reactants, and solvation of ions. Solvation will be important for any reactions in which charge is created, destroyed or transferred, including intra-molecular charge redistribution, which, for example, leads to giant dipole formation in excited states.

Work performed under the auspices of the Office of Basic Energy Sciences, Division of Chemical Science, US-DOE undercontract number W-31-109-ENG-38.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Log in via an institution
Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 169.00
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 219.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 219.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. Reichardt, C., Solvents and Solvent Effects in Organic Chemistry, 1988, VCH, Weinheim, FRG.

    Google Scholar 

  2. Baxendale, J. H. and Wardman, P., J. Chem. Soc. Faraday Trans.,169, 584 (1973).

    Google Scholar 

  3. Baxendale, J. H. and Wardman, P., Can. J. Chem.,55, 1996 (1977).

    Article  CAS  Google Scholar 

  4. Gilles, L., Bono, M. R., and Schmidt, M., Can. J. Chem., 55, 2003 (1977).

    Article  CAS  Google Scholar 

  5. Okazaki, K. and Freeman, G. R., Can. J. Chem.,56, 2305 (1978).

    Article  CAS  Google Scholar 

  6. Kevan, L., J. Phys. Chem.,84, 1232 (1980); Acct. Chem. Res., 14,138 (1981).

    Article  CAS  Google Scholar 

  7. Chase, W. J. and Hunt, J. W., J. Phys. Chem., 79, 2835 (1975).

    Article  CAS  Google Scholar 

  8. Kenney-Wallace, G. A. and Jonah, C. D., Chem. Phys. Lett., 39, 596 (1976); J. Phys. Chem., 2572 (1982).

    Article  CAS  Google Scholar 

  9. Migus, A., Gauduel, Y., Martin, J. L., and Antonetti, A., Phys. Rev. Lett.,58, 1559 (1987).

    Google Scholar 

  10. Wang, Y, McAuliffe, M., Novak, F., and Eisenthal, K. B., J. Phys. Chem.,85, 3736 (1981).

    Google Scholar 

  11. Huppert, D., Rand, S. D., Rentzepis, P. M, Barbara, P. F., Struve, W. S., and Grabowski, Z. R., J. Chem. Phys.,75, 5714 (1981).

    Article  CAS  Google Scholar 

  12. Castner, Jr., E. W., Maroncelli, M., and Fleming, G. R., J. Chem. Phys.,86, 1090 (1987).

    CAS  Google Scholar 

  13. Maroncelli, M. and Fleming, G. R., J. Chem. Phys.,86, 6221 (1987).

    Article  CAS  Google Scholar 

  14. Simon, J. D. and Su, S. G., J. Chem. Phys.,87, 7016 (1987).

    Article  CAS  Google Scholar 

  15. Su, S. G. and Simon, J. D., J. Phys. Chem.,91,2693 (1987).

    Article  CAS  Google Scholar 

  16. Declémy, A., Rullière, C, and Kottis, Ph., Chem. Phys. Lett.,133,448 (1987).

    Google Scholar 

  17. Declémy, A. and Rullière, C, Chem. Phys. Lett.,146, 1 (1988).

    Article  Google Scholar 

  18. Nagarajan, V, Brearley, A. M., Kang, T.-J., and Barbara, P. F., J. Chem. Phys.,86, 3183 (1987).

    Article  CAS  Google Scholar 

  19. Chapman, C. F., Fee, R. S., and Maroncelli, M., J. Phys. Chem.,94, 4929 (1990).

    Article  CAS  Google Scholar 

  20. Jauquet, M. and Laszlo, P., Influence of Solvents on Spectroscopy, in Dack, M. R. J. (ed.) Solutions and Solubilities. Vol. VIII, Part I of Weissberger, A. (ed.) Techniques of Chemistry, Wiley-Interscience New York, 1975.

    Google Scholar 

  21. Amos, A. T. and Barrows, B. L., Adv. Quantum Chem.,7, 289 (1973).

    Article  CAS  Google Scholar 

  22. Nicol, M. F., Appl. Spectrosc. Rev., 8, 183 (1974).

    Article  CAS  Google Scholar 

  23. Davis, K. M. C, Solvent Effects on Charge-Transfer Complexes in Forster, R. (ed.) Molecular Association, Academic Press, London, New York (1975), VI.

    Google Scholar 

  24. Rips, I., Klafter, J., and Jortner, J., J. Chem. Phys.,89, 3246 (1988); J. Chem. Phys., 89, 4288 (1988).

    Article  Google Scholar 

  25. Kenney-Wallace, G., Adv. Chem. Phys.,47, 535 (1981).

    Article  CAS  Google Scholar 

  26. Simon, J. D., Acc. Chem. Res.,21, 128 (1988).

    Article  CAS  Google Scholar 

  27. Fleming, G. R., Chemical Applications of Ultrafast Spectroscopy,(1986). New York, Oxford.

    Google Scholar 

  28. Maroncelli, M., J. Mol. Liquids.,(1992), in press.

    Google Scholar 

  29. Barbara, P. F. and Jarzeba, W, Acc. Chem. Res.,21, 195 (1988).

    Article  CAS  Google Scholar 

  30. Kosower, E. M. and Huppert, D., Annu. Rev. Phys. Chem.,37, 127 (1986).

    Article  CAS  Google Scholar 

  31. Bagchi, B., Annu. Rev. Phys. Chem.,40, 115 (1989).

    Article  CAS  Google Scholar 

  32. Bakhshiev, N. G., Opt. Spectrosc.(USSR), 16, 446 (1964).

    Google Scholar 

  33. Mazurenko, Yu. T., Opt. Spectrosc.(USSR), 36, 283 (1974).

    Google Scholar 

  34. Bagchi, B., Oxtoby, D. W, and Fleming, G. R., Chem. Phys.,86, 257 (1984).

    Article  CAS  Google Scholar 

  35. Van der Zwan and Hynes, J. T., J. Phys. Chem.,89, 4181 (1985).

    Article  Google Scholar 

  36. Kahlow, M. A., Kang, T.-J., and Barbara, P. F., J. Chem. Phys., 88, 2372 (1988).

    Article  CAS  Google Scholar 

  37. Jarzeba, W, Walker, G. C, Johnson, A. E., Kahlow, M. A., and Barbara, P. F, J. Chem. Phys., 92, 7039 (1988).

    Article  CAS  Google Scholar 

  38. Bottchev, C. J. F. and Bordewijk, P., Theory of Electric Polarization,Vol. 2, (Elsevier, New York, 1978).

    Google Scholar 

  39. Castner, E. W. Jr., Fleming, G. R., and Bagchi, B., Chem. Phys. Lett.,143, 270 (1988).

    Article  CAS  Google Scholar 

  40. Ehrenson, S., J. Phys. Chem.,91, 1868 (1987).

    Article  CAS  Google Scholar 

  41. Bagchi, B., Castner, E. W. Jr., and Fleming, G. R., J. Mol. Struc. Theor. Chem.,194, 171 (1989).

    Article  CAS  Google Scholar 

  42. Castner, E. W. Jr., Fleming, G. R., Bagchi, B., and Maroncelli, M., J. Chem. Phys.,89, 3519 (1988).

    Article  CAS  Google Scholar 

  43. Wolynes, P. G., J. Chem. Phys.,86, 5133 (1987).

    Article  CAS  Google Scholar 

  44. Nichols III, A. L. and Calef, D. F, J. Chem. Phys.,89, 3783 (1988).

    Article  CAS  Google Scholar 

  45. Calef, D. F. and Wolynes, P. G., J. Chem. Phys.,78,4145 (1983).

    Article  CAS  Google Scholar 

  46. Chandra, A. and Bagchi, B., Chem. Phys. Lett.,151,47 (1988).

    Article  CAS  Google Scholar 

  47. Bagchi, B. and Chandra, A., J. Chem. Phys.,90, 7338 (1989).

    Article  Google Scholar 

  48. Gray, C. G. and Gubbins, K. E., Theory of Molecular Fluids, Vol. 1. Oxford, Clarendon (1984).

    Google Scholar 

  49. Chandra, A. and Bagchi, B., J. Phys. Chem.,93, 6996 (1989).

    Article  CAS  Google Scholar 

  50. Fonseca, T. and Ladanyi, B. J. Phys. Chem.,95,2116 (1991).

    Article  CAS  Google Scholar 

  51. Maroncelli, M., J. Chem. Phys.,94, 2048 (1991).

    Article  Google Scholar 

  52. Lin, Y. and Jonah, C. D., Chem. Phys. Lett.,191, 357 (1992).

    Article  Google Scholar 

  53. Jonah, C. D., Rev. Sci. Instrum.,46, 62 (1975).

    Article  CAS  Google Scholar 

  54. Jonah, C. D. and Kenney-Wallace, G. A., in Proceedings of Sixth International Congress of Radiation Research, Okada, S. (ed.); Tokyo (1979).

    Google Scholar 

  55. Lin, Y. and Jonah, C. D., J. Phys. Chem.,(1992).

    Google Scholar 

  56. Lewis, M., Trans. Faraday Soc,57,1686 (1961).

    Article  Google Scholar 

  57. Beckett, A. and Porter, G., Trans. Fraraday Soc.,59,2038 (1963).

    Article  CAS  Google Scholar 

  58. Adams, G. E., Baxendale, J. H., and Boag, J. W., Proc. Roy. Soc.,A277,549 (1964).

    Google Scholar 

  59. Marignier, J. L. and Hickel, B., Chem. Phys. Lett.,86, 95 (1982).

    Article  CAS  Google Scholar 

  60. Marignier, J. L. and Hickel, B., J. Phys. Chem.,88, 5375 (1984).

    Article  CAS  Google Scholar 

  61. Papazyan, A. and Maroncelli, M., J. Chem. Phys.,95, 9219 (1991).

    Article  CAS  Google Scholar 

  62. Fujisaki, N., Comte, P., Infelta, P. P., and Gaumann, T., J. Phys. Chem.,95, 6259 (1991).

    Article  CAS  Google Scholar 

  63. Leu, A. D., Jha, K. N., and Freeman, G. R., Can. J. Chem.,60, 2342 (1982).

    Article  CAS  Google Scholar 

  64. Hentz, R. R. and Kenney-Wallace, G. A., J. Phys. Chem.,76, 2931 (1972).

    Article  CAS  Google Scholar 

  65. Hentz, R. R. and Kenney-Wallace, G. A., J. Phys. Chem.,78, 514 (1974).

    Article  CAS  Google Scholar 

  66. Rosenthal, S. J., Xie, X., Du, M., and Fleming, G. R., J. Chem. Phys,95, 4715 (1991).

    Article  CAS  Google Scholar 

  67. Levesque, D., Weis, J.-J., and Hansen, J.-P., Simulation of Classical Fluids,Binder, K. (ed.) Monte Carlo Methods in Statistical Physics, Springer-Verlag, Berlin, Heidelberg (1986).

    Google Scholar 

  68. Lin, Y. and Jonah, C. D., submitted to J. Phys. Chem.

    Google Scholar 

  69. Jansoone, V. M., Chem. Phys.,3, 78 (1974).

    Article  CAS  Google Scholar 

  70. Allen, M. P. and Tildesley, D. J., Computer Simulation of Liquids, Oxford, Clarendon, (1990).

    Google Scholar 

  71. Long, F. H., Lu, H., and Eisenthal, K. B., J. Chem. Phys.,91, 4413 (1989).

    Article  CAS  Google Scholar 

  72. Long, F. H., Lu, H., and Eisenthal, K. B., Phys. Rev. Lett.,64, 1469 (1990).

    Article  CAS  Google Scholar 

  73. Loring, R. F. and Mukamel, S., J. Chem. Phys.,87, 1272 (1987).

    Article  CAS  Google Scholar 

  74. Dye, J. L., DeBacker, M. G., and Dorfman, L. M., J. Chem. Phys.,52, 6251 (1970).

    Article  CAS  Google Scholar 

  75. Dorfman, L. M. and Jou, F. Y, in Electrons in Fluids, Jortner, J. and Kesner, N. R. (ed.) Springer-Verlag, New York, p447 (1973).

    Chapter  Google Scholar 

  76. Garg, S. K. and Smyth, C. P., J. Phys. Chem.,69,1294 (1965).

    Article  CAS  Google Scholar 

  77. Davies, M., Dielectric Properties and Molecular Behavior, Hill, N. E.; Vaughan, W. E.; Price, A. H.; Davies, M., (ed.), Van Nostrand, London, (1969).

    Google Scholar 

  78. Barthel, J., Bachhuber, K., Büchner, R., Gill, J. B., and Kleebauer, M., Chem. Phys. Lett., 167, 62 (1990).

    Article  CAS  Google Scholar 

  79. Barthel, J., Bachhuber, K., Büchner, R., and Hetzenauer, H., Chem. Phys. Lett.,165, 369 (1990).

    Article  CAS  Google Scholar 

  80. Su, S.-G. and Simon, J. D., J. Phys. Chem.,93, 753 (1989).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Chemistry Division, Argonne National Laboratory Argonne, IL, 60439, USA

    Y. Lin & C. D. Jonah

Authors
  1. Y. Lin
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. C. D. Jonah
    View author publications

    You can also search for this author in PubMed Google Scholar

Editor information

Editors and Affiliations

  1. Department of Chemistry, University of California, San Diego, La Jolla, California, USA

    John D. Simon

Rights and permissions

Reprints and permissions

Copyright information

© 1994 Springer Science+Business Media Dordrecht

About this chapter

Cite this chapter

Lin, Y., Jonah, C.D. (1994). The Dynamics of Anion Solvation in Alcohols. In: Simon, J.D. (eds) Ultrafast Dynamics of Chemical Systems. Understanding Chemical Reactivity, vol 7. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-0916-1_4

Download citation

  • DOI: https://doi.org/10.1007/978-94-011-0916-1_4

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-94-010-4395-3

  • Online ISBN: 978-94-011-0916-1

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics

Search

Navigation